Phenol is approximately how much times acidic than ethanol?a)10b)25c)1...
Phenol is a compound that contains a hydroxyl (-OH) group attached to an aromatic ring. Ethanol, on the other hand, is an alcohol that contains a hydroxyl group (-OH) attached to a saturated carbon atom. The presence of the aromatic ring in phenol makes it more acidic compared to ethanol.
Phenol is a stronger acid than ethanol due to the following reasons:
1. Stability of the phenoxide ion:
- The conjugate base of phenol, known as the phenoxide ion, is stabilized by resonance delocalization.
- The negative charge on the oxygen atom in the phenoxide ion can be delocalized throughout the aromatic ring, making it more stable.
- This resonance stabilization contributes to the acidity of phenol.
2. Inductive effect:
- The presence of the aromatic ring in phenol increases the electron density on the oxygen atom of the hydroxyl group.
- This increased electron density makes the oxygen atom more electronegative and facilitates the release of the hydrogen ion (H+), making phenol more acidic.
3. Effect of aromaticity:
- Aromatic compounds, such as phenol, have a higher degree of stability compared to non-aromatic compounds.
- This stability is due to the delocalization of pi electrons in the aromatic ring, which provides additional stability to the phenol molecule.
- The presence of an aromatic ring in phenol contributes to its increased acidity compared to ethanol.
Based on these factors, phenol is approximately a million times more acidic than ethanol. The resonance stabilization of the phenoxide ion, the inductive effect, and the effect of aromaticity all contribute to the enhanced acidity of phenol.
Phenol is approximately how much times acidic than ethanol?a)10b)25c)1...
Phenol is more acidic than alcohols because of their better stability and resonant structures. The pKa values of phenol and ethanol are 10 and 15.9 respectively, which when converted to Ka values gives a ratio of about a million.