Does the degree of hydration depend upon the size of the cation?a)Yesb...
The degree of hydration depends upon the size of the cation, smaller the size of the cation, greater is its hydration enthalpy. The relative degree of hydration in an increasing order is Li+ > Na+ > K+ > Rb+ > Cs+.
Does the degree of hydration depend upon the size of the cation?a)Yesb...
Answer:
The degree of hydration refers to the number of water molecules that are directly coordinated to a cation in a hydrated compound. It is a measure of the extent of the hydration of the cation.
Explanation:
The size of the cation does indeed influence the degree of hydration. Here's why:
1. Coordination Number:
The size of the cation affects the coordination number, which is the number of atoms or ions immediately surrounding a central atom in a complex or crystal. In hydrated compounds, the cation is usually surrounded by water molecules. The coordination number determines how many water molecules can coordinate with the cation.
2. Ionic Radius:
The size of a cation is determined by its ionic radius. Smaller cations have a higher charge density because the positive charge is concentrated in a smaller space. This higher charge density attracts more water molecules, resulting in a higher degree of hydration. Conversely, larger cations have a lower charge density and can accommodate fewer water molecules, leading to a lower degree of hydration.
3. Electrostatic Interactions:
The degree of hydration also depends on the strength of the electrostatic interactions between the cation and water molecules. Smaller cations with a higher charge density have stronger attractions to water molecules, resulting in a higher degree of hydration. Larger cations with a lower charge density have weaker attractions to water, leading to a lower degree of hydration.
4. Hydration Energy:
The size of the cation also affects the hydration energy, which is the energy released when a cation is hydrated. Smaller cations with a higher charge density have a larger hydration energy because the water molecules can get closer to the cation, resulting in stronger interactions. Larger cations with a lower charge density have a smaller hydration energy because the water molecules are farther away from the cation and the interactions are weaker.
Conclusion:
In summary, the degree of hydration is influenced by the size of the cation. Smaller cations with a higher charge density have a higher degree of hydration due to their higher coordination number, stronger electrostatic interactions, and larger hydration energy. On the other hand, larger cations with a lower charge density have a lower degree of hydration because they can accommodate fewer water molecules and have weaker electrostatic interactions and hydration energy. Therefore, the correct answer is option 'A' - Yes, the degree of hydration depends upon the size of the cation.