In which of the following compound will chlorine show the highest oxid...
To understand it better, first, we will calculate the oxidation state of HCl, HClO4, and KClO3.
The oxidation state of chlorine in HCl will be
1 + x = 0
x = – 1
The oxidation state of chlorine in HClO4 will be:
1 + x + 4 X ( -2) = 0
1 + x – 8 = 0
x – 7 = 0
x = + 7
The oxidation state of chlorine in KClO3 will be
1 + x + 3 X ( -2 ) = 0
1 + x – 6 = 0
x = + 5
Hence the oxidation state of chlorine is maximum in HClO4, i.e. equivalent to + 7.
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In which of the following compound will chlorine show the highest oxid...
Explanation:
Chlorine can exhibit different oxidation states depending on the compound it is present in. The highest oxidation state of chlorine is +7, and it is found in compounds where chlorine is bonded to highly electronegative elements such as oxygen.
Analysis of options:
a) HCl: In hydrochloric acid (HCl), chlorine is in the -1 oxidation state. This is because hydrogen has an oxidation state of +1, and the overall charge of the compound is 0. Chlorine is more electronegative than hydrogen, so it takes the negative oxidation state of -1.
b) HClO4: In perchloric acid (HClO4), chlorine is in the +7 oxidation state. This is because oxygen is highly electronegative, and each oxygen atom in the molecule contributes -2 to the overall charge. The hydrogen atom has an oxidation state of +1, so chlorine must have an oxidation state of +7 to balance the charges. Therefore, chlorine shows the highest oxidation state in HClO4.
c) KClO3: In potassium chlorate (KClO3), chlorine is in the +5 oxidation state. This is because oxygen contributes -2 to the overall charge, and potassium has an oxidation state of +1. Chlorine must have an oxidation state of +5 to balance the charges.
d) None of the above: The only compound in the given options where chlorine shows the highest oxidation state is HClO4 (perchloric acid). Therefore, the correct answer is option B.
Summary:
Chlorine shows the highest oxidation state of +7 in perchloric acid (HClO4) because it is bonded to highly electronegative oxygen atoms. In the other compounds, chlorine has lower oxidation states.
In which of the following compound will chlorine show the highest oxid...
To understand it better, first, we will calculate the oxidation state of HCl, HClO4, and KClO3.
The oxidation state of chlorine in HCl will be
1 + x = 0
x = – 1
The oxidation state of chlorine in HClO4 will be:
1 + x + 4 X ( -2) = 0
1 + x – 8 = 0
x – 7 = 0
x = + 7
The oxidation state of chlorine in KClO3 will be
1 + x + 3 X ( -2 ) = 0
1 + x – 6 = 0
x = + 5
Hence the oxidation state of chlorine is maximum in HClO4, i.e. equivalent to + 7.