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How many isomers of c5h8o on treatment with 2,4-dinitrophenyl hydrazine gives orange precipitate (including stereo isomers)?
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How many isomers of c5h8o on treatment with 2,4-dinitrophenyl hydrazin...
B

To determine the number of isomers of C5H8O that give an orange precipitate upon treatment with 2,4-dinitrophenyl hydrazine, we need to consider the possible structures and their stereochemistry.

b
C5H8O can have different structural arrangements based on the connectivity of the carbon, hydrogen, and oxygen atoms. The possible structures include:

1. Aldehyde: C=O at the terminal carbon of the chain.
2. Ketone: C=O in the middle of the carbon chain.
3. Hydroxyketone: C=O in the middle of the carbon chain with an adjacent hydroxyl group.

b
When treated with 2,4-dinitrophenyl hydrazine, compounds containing a carbonyl group (aldehyde, ketone, or hydroxyketone) react to form a yellow to orange precipitate known as a dinitrophenylhydrazone. This reaction is commonly used for the identification and characterization of carbonyl compounds.

b
To determine the number of isomers, we need to consider the different possibilities for each structural arrangement and the possible stereochemistry. Let's analyze each possibility:

1. Aldehyde:
- There is only one aldehyde structure for C5H8O, which is pentanal (CH3CH2CH2CH2CHO).
- Pentanal can exist as a straight-chain isomer or as different branched isomers.
- Considering the stereochemistry, pentanal can also have different stereoisomers based on the arrangement of substituents around the chiral carbon (if present).

2. Ketone:
- There is only one ketone structure for C5H8O, which is pentan-2-one (CH3CH2COCH3).
- Pentan-2-one can exist as different positional isomers (isomers with the carbonyl group at different positions in the carbon chain).
- Considering the stereochemistry, pentan-2-one can also have different stereoisomers based on the arrangement of substituents around the chiral carbon (if present).

3. Hydroxyketone:
- There are two possible hydroxyketone structures for C5H8O: 3-hydroxypentan-2-one and 2-hydroxypentan-3-one.
- Both hydroxyketones can exist as different positional isomers.
- Considering the stereochemistry, each hydroxyketone can have different stereoisomers based on the arrangement of substituents around the chiral carbon (if present).

b
In conclusion, the number of isomers of C5H8O on treatment with 2,4-dinitrophenyl hydrazine that give an orange precipitate includes the different possibilities for aldehydes, ketones, and hydroxyketones. The exact number of isomers would depend on the specific stereochemistry and positional isomerism of each structure. Considering the potential stereochemistry and positional isomerism, the total number of isomers could be quite large. It is advisable to use a molecular modeling software or consult a reliable
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How many isomers of c5h8o on treatment with 2,4-dinitrophenyl hydrazine gives orange precipitate (including stereo isomers)?
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