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An octahedral complex with molecular composition M.5NH3.Cl.SO4 has two isomers, A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCl2 solution.
The type of isomerism exhibited by the complex is :
The type of isomerism exhibited by the complex is :
- a)Geometrical isomerism
- b)Coordinate isomerism
- c)Ionisation isomerism
- d)Linkage isomerism
Correct answer is option 'C'. Can you explain this answer?
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An octahedral complex with molecular composition M.5NH3.Cl.SO4 has two...
Correct answer will be ionisation isomerism as in A isomer chloride ion is present out of the coordination sphere whereas in B sulphate ion is there ...
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An octahedral complex with molecular composition M.5NH3.Cl.SO4 has two...
Understanding Isomerism in Coordination Compounds
The complex M.5NH3.Cl.SO4 can exhibit different types of isomerism. Let's explore why the correct answer is ionization isomerism.
Definition of Ionization Isomerism
- Ionization isomerism occurs when two isomers have the same molecular formula but differ in the ions that are released into the solution upon dissociation.
- In this case, the different anions (Cl- and SO4^2-) can lead to the formation of different soluble species.
Analysis of Isomers A and B
- Isomer A: When this isomer is dissolved, it releases Cl- ions into the solution.
- Observation: It gives a white precipitate with AgNO3 solution, indicating the presence of Cl- ions (which form AgCl precipitate).
- Isomer B: When this isomer is dissolved, it releases SO4^2- ions instead.
- Observation: It gives a white precipitate with BaCl2 solution, indicating the presence of SO4^2- ions (which form BaSO4 precipitate).
Conclusion
- Since the two isomers differ in the anions that are released into the solution (Cl- in A and SO4^2- in B), this confirms that M.5NH3.Cl.SO4 exhibits ionization isomerism.
- Therefore, the correct answer is option C: Ionization isomerism.
This example illustrates how the composition of coordination compounds can lead to different chemical behaviors based on their structural arrangements.
The complex M.5NH3.Cl.SO4 can exhibit different types of isomerism. Let's explore why the correct answer is ionization isomerism.
Definition of Ionization Isomerism
- Ionization isomerism occurs when two isomers have the same molecular formula but differ in the ions that are released into the solution upon dissociation.
- In this case, the different anions (Cl- and SO4^2-) can lead to the formation of different soluble species.
Analysis of Isomers A and B
- Isomer A: When this isomer is dissolved, it releases Cl- ions into the solution.
- Observation: It gives a white precipitate with AgNO3 solution, indicating the presence of Cl- ions (which form AgCl precipitate).
- Isomer B: When this isomer is dissolved, it releases SO4^2- ions instead.
- Observation: It gives a white precipitate with BaCl2 solution, indicating the presence of SO4^2- ions (which form BaSO4 precipitate).
Conclusion
- Since the two isomers differ in the anions that are released into the solution (Cl- in A and SO4^2- in B), this confirms that M.5NH3.Cl.SO4 exhibits ionization isomerism.
- Therefore, the correct answer is option C: Ionization isomerism.
This example illustrates how the composition of coordination compounds can lead to different chemical behaviors based on their structural arrangements.
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An octahedral complex with molecular composition M.5NH3.Cl.SO4 has two isomers, A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCl2 solution.The type of isomerism exhibited by the complex is :a)Geometrical isomerismb)Coordinate isomerismc)Ionisation isomerismd)Linkage isomerismCorrect answer is option 'C'. Can you explain this answer?
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An octahedral complex with molecular composition M.5NH3.Cl.SO4 has two isomers, A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCl2 solution.The type of isomerism exhibited by the complex is :a)Geometrical isomerismb)Coordinate isomerismc)Ionisation isomerismd)Linkage isomerismCorrect answer is option 'C'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about An octahedral complex with molecular composition M.5NH3.Cl.SO4 has two isomers, A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCl2 solution.The type of isomerism exhibited by the complex is :a)Geometrical isomerismb)Coordinate isomerismc)Ionisation isomerismd)Linkage isomerismCorrect answer is option 'C'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for An octahedral complex with molecular composition M.5NH3.Cl.SO4 has two isomers, A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCl2 solution.The type of isomerism exhibited by the complex is :a)Geometrical isomerismb)Coordinate isomerismc)Ionisation isomerismd)Linkage isomerismCorrect answer is option 'C'. Can you explain this answer?.
An octahedral complex with molecular composition M.5NH3.Cl.SO4 has two isomers, A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCl2 solution.The type of isomerism exhibited by the complex is :a)Geometrical isomerismb)Coordinate isomerismc)Ionisation isomerismd)Linkage isomerismCorrect answer is option 'C'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about An octahedral complex with molecular composition M.5NH3.Cl.SO4 has two isomers, A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCl2 solution.The type of isomerism exhibited by the complex is :a)Geometrical isomerismb)Coordinate isomerismc)Ionisation isomerismd)Linkage isomerismCorrect answer is option 'C'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for An octahedral complex with molecular composition M.5NH3.Cl.SO4 has two isomers, A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCl2 solution.The type of isomerism exhibited by the complex is :a)Geometrical isomerismb)Coordinate isomerismc)Ionisation isomerismd)Linkage isomerismCorrect answer is option 'C'. Can you explain this answer?.
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