JEE Exam  >  JEE Questions  >  The number of geometrical isomers of the octa... Start Learning for Free
The number of geometrical isomers of the octahedral complex of the type [Mabcdef] is n x 3. . The value of n is
    Correct answer is '5'. Can you explain this answer?
    Verified Answer
    The number of geometrical isomers of the octahedral complex of the typ...
    Total 15 gemetrical isomers
    View all questions of this test
    Most Upvoted Answer
    The number of geometrical isomers of the octahedral complex of the typ...
    The answer is 30.
    first consider how many distinct rods of x-M-y can be made (a-M-b and b-M-a are the same) .
    No. of such ways = 6!((2!^3)*3!)=15
    now consider a situation→ a-M-c; b-M-d; e-M-f are the three possible rods as shown in figure
    align the rods with the x-y-z axis with M as origin in any order you want.
    lets call M-c as the vector from M to point c hence we see that Ma= -Mc and as such it follows all vector properties . Also take |Mc|=1 just to keep it simple.
    This is the tricky part now:
    if you define a rule that (Mb X Me= Mc)→eq1; (X here is cross product) whenever you combine the above given rods ,then you can check for yourself that there is a unique octahedron( in fig above) and rotating about any of x, y or z axis wont make any change in relative positions of molecules . In fact if you fix the relative positioning of any three points(e ,b ,c lets say) then the octahedron becomes unique. You can also define (Mc X Md= -Mf )→eq2 ;but you’ll see that eq2 is just eq 1 written in another way( just take cross product with Md ).
    But if we defined (Mb X Me = Ma) then the octahedron would have been different one in which a & c have switched places. In fact it would be the mirror image of the octahedron shown above. And as a result all the relative positions of any three molecules which are not on same rod will also change! All the cross products which were +ve become -ve now . Cross products are basically a rotation property. Hence there are enantiomeric pairs.
    So we see we have two such rules for 3 given rods, hence total no. of such combinations possible = 15 *2= 30.
    n×3=15...so value of n is 5
    Explore Courses for JEE exam
    The number of geometrical isomers of the octahedral complex of the type [Mabcdef] is n x 3. . The value of n isCorrect answer is '5'. Can you explain this answer?
    Question Description
    The number of geometrical isomers of the octahedral complex of the type [Mabcdef] is n x 3. . The value of n isCorrect answer is '5'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about The number of geometrical isomers of the octahedral complex of the type [Mabcdef] is n x 3. . The value of n isCorrect answer is '5'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for The number of geometrical isomers of the octahedral complex of the type [Mabcdef] is n x 3. . The value of n isCorrect answer is '5'. Can you explain this answer?.
    Solutions for The number of geometrical isomers of the octahedral complex of the type [Mabcdef] is n x 3. . The value of n isCorrect answer is '5'. Can you explain this answer? in English & in Hindi are available as part of our courses for JEE. Download more important topics, notes, lectures and mock test series for JEE Exam by signing up for free.
    Here you can find the meaning of The number of geometrical isomers of the octahedral complex of the type [Mabcdef] is n x 3. . The value of n isCorrect answer is '5'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of The number of geometrical isomers of the octahedral complex of the type [Mabcdef] is n x 3. . The value of n isCorrect answer is '5'. Can you explain this answer?, a detailed solution for The number of geometrical isomers of the octahedral complex of the type [Mabcdef] is n x 3. . The value of n isCorrect answer is '5'. Can you explain this answer? has been provided alongside types of The number of geometrical isomers of the octahedral complex of the type [Mabcdef] is n x 3. . The value of n isCorrect answer is '5'. Can you explain this answer? theory, EduRev gives you an ample number of questions to practice The number of geometrical isomers of the octahedral complex of the type [Mabcdef] is n x 3. . The value of n isCorrect answer is '5'. Can you explain this answer? tests, examples and also practice JEE tests.
    Explore Courses for JEE exam

    Top Courses for JEE

    Explore Courses
    Signup for Free!
    Signup to see your scores go up within 7 days! Learn & Practice with 1000+ FREE Notes, Videos & Tests.
    10M+ students study on EduRev