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Which of the following statements most accurately describes the details of the hybridization of sulfur hexafluoride?
  • a)
    The sulfur atom undergoes excitation to promote two electrons from the 2s orbital to two empty 3d orbitals.
  • b)
    Sulfur forms six σ hybridized bonds with fluorine atoms, and each fluorine atom makes use of a half-filled 3pz orbital for the bond formation.
  • c)
    The orbitals are all oriented such that all bond angles are 90° and have an octahedral configuration.
  • d)
    In the excited state, intermixing of one s, three p and three d orbitals gives 6 half-filled sp2d3 hybrid orbitals.
Correct answer is option 'C'. Can you explain this answer?
Most Upvoted Answer
Which of the following statements most accurately describes the detail...
Understanding Sulfur Hexafluoride Hybridization
Sulfur hexafluoride (SF6) is a molecular compound where sulfur is centrally located and bonded to six fluorine atoms. The hybridization and bonding details provide insight into its geometric structure.
Excitation and Hybridization
- In the formation of SF6, the sulfur atom undergoes excitation, where an electron from the 3s orbital is promoted to the 3d orbital. This is crucial for accommodating six bonding pairs.
- Sulfur utilizes one 3s orbital, three 3p orbitals, and two 3d orbitals to create six equivalent hybrid orbitals known as sp3d2 hybrid orbitals.
Bond Formation
- Each of the six sp3d2 hybrid orbitals forms a sigma bond with a fluorine atom. Each fluorine atom contributes a half-filled 2p orbital for bond formation.
Molecular Geometry
- The resulting molecular geometry of SF6 is octahedral. This configuration allows for optimal spatial arrangement of the bonded fluorine atoms.
- The bond angles in an octahedral structure are exactly 90 degrees, confirming that the statement regarding bond angles in option 'C' is accurate.
Conclusion
- The hybridization of sulfur in SF6 is a clear example of how electron promotion and orbital hybridization lead to specific molecular geometries, confirming that option 'C' accurately describes the details of sulfur hexafluoride hybridization.
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Community Answer
Which of the following statements most accurately describes the detail...
The sulfur atom undergoes excitation to promote two electrons, one from 3s and one from 3p, not two from 2s, to two empty 3d orbitals.
In the excited state, the intermixing of one s, three p, and two, not three d, orbitals gives 6 half-filled sp2d3, not sp2d3,, hybridized orbitals.
Sulfur forms 6 σ hybridized bonds with fluorine atoms , and each fluorine atom makes use of a half-filled 2pz, not 3pz, orbital for the bond formation.
The orbitals are all oriented such that all bond angles are 90° and have an octahedral configuration is the correct answer.
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Which of the following statements most accurately describes the details of the hybridization of sulfur hexafluoride?a)The sulfur atom undergoes excitation to promote two electrons from the 2s orbital to two empty 3d orbitals.b)Sulfur forms six σ hybridized bonds with fluorine atoms, and each fluorine atom makes use of a half-filled 3pz orbital for the bond formation.c)The orbitals are all oriented such that all bond angles are 90° and have an octahedral configuration.d)In the excited state, intermixing of one s, three p and three d orbitals gives 6 half-filled sp2d3 hybrid orbitals.Correct answer is option 'C'. Can you explain this answer? for MCAT 2025 is part of MCAT preparation. The Question and answers have been prepared according to the MCAT exam syllabus. Information about Which of the following statements most accurately describes the details of the hybridization of sulfur hexafluoride?a)The sulfur atom undergoes excitation to promote two electrons from the 2s orbital to two empty 3d orbitals.b)Sulfur forms six σ hybridized bonds with fluorine atoms, and each fluorine atom makes use of a half-filled 3pz orbital for the bond formation.c)The orbitals are all oriented such that all bond angles are 90° and have an octahedral configuration.d)In the excited state, intermixing of one s, three p and three d orbitals gives 6 half-filled sp2d3 hybrid orbitals.Correct answer is option 'C'. Can you explain this answer? covers all topics & solutions for MCAT 2025 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the following statements most accurately describes the details of the hybridization of sulfur hexafluoride?a)The sulfur atom undergoes excitation to promote two electrons from the 2s orbital to two empty 3d orbitals.b)Sulfur forms six σ hybridized bonds with fluorine atoms, and each fluorine atom makes use of a half-filled 3pz orbital for the bond formation.c)The orbitals are all oriented such that all bond angles are 90° and have an octahedral configuration.d)In the excited state, intermixing of one s, three p and three d orbitals gives 6 half-filled sp2d3 hybrid orbitals.Correct answer is option 'C'. Can you explain this answer?.
Solutions for Which of the following statements most accurately describes the details of the hybridization of sulfur hexafluoride?a)The sulfur atom undergoes excitation to promote two electrons from the 2s orbital to two empty 3d orbitals.b)Sulfur forms six σ hybridized bonds with fluorine atoms, and each fluorine atom makes use of a half-filled 3pz orbital for the bond formation.c)The orbitals are all oriented such that all bond angles are 90° and have an octahedral configuration.d)In the excited state, intermixing of one s, three p and three d orbitals gives 6 half-filled sp2d3 hybrid orbitals.Correct answer is option 'C'. Can you explain this answer? in English & in Hindi are available as part of our courses for MCAT. Download more important topics, notes, lectures and mock test series for MCAT Exam by signing up for free.
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