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The value of a in van der Waal equation is _________ /dependent on _________.
  • a)
    pressure
  • b)
    temperature
  • c)
    pressure and temperature
  • d)
    independent of pressure and temperature
Correct answer is option 'D'. Can you explain this answer?
Verified Answer
The value of a in van der Waal equation is _________ /dependent on ___...
Value of an in van der Waal equation represents a measure of the magnitude of intermolecular attractive forces within the gas and it is also independent of temperature and pressure. The van der Waal’s equation is given by (P – an2/V2)(V – nb) = nRT.
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There are two types of forces that occur with all substances on Earth. Intramolecular forces occur between atoms in a molecule, while intermolecular forces occur between neighboring molecules. Intermolecular forces can be dipole-dipole forces, hydrogen bonding, or London dispersion forces.Professor 1:Water molecules represent an example of hydrogen bonding due to the attraction between the hydrogen atoms and the oxygen atoms in the molecule. This strong dipole-dipole occurs due to lone pairs present on such atoms as Fluorine, Nitrogen, and Oxygen, which are able to pair more closely to the hydrogen atom in another nearby molecule. Water can be present in a solid, liquid, or gaseous state on Earth depending on the competition between the strength of intermolecular bonds and the thermal energy of the system. In 1873, a Dutch scientist, Van der Waals derived an equation that included both the force of attraction between the particles of a gas and the volume of the particles at high pressures. This equation led to a better fit for experimental data than the Ideal Gas Law.Professor 2:Water is the only substance on Earth that we routinely encounter as a solid, liquid, and gas. At low temperatures, the water molecules lock into a rigid structure, but as the temperature increases, the average kinetic energy of the water molecules increases and the molecules are able to move more creating its other natural states of matter. The higher the temperature, the more likely water is to be a gas. Water is proof of the kinetic theory, which assumes that there is no force of attraction between the particles of the gas state. The best fit for experimental data involving water in a gaseous form is found by using the Ideal Gas Law, since there is no interaction between the gaseous molecules. This law accounts for all of the forces that occur with gases on Earth.Q. Which of the following statements would professor 2 agree with?

Chemists can model how solids, liquids, and gases behave at different temperatures and pressures with a graph called a phase diagram. When the pressure and temperature are simultaneously known, a scientist can predict whether the material will be in a specific state. The diagram is divided into sections depending on the phase and the lines between sections represent phase transitions occurring between two or more separate phases.In general, solids of neatly stacked molecules exist when temperatures are low and pressures are intermediate. These values decrease the kinetic energy of the molecules enough to allow for attractive forces to begin the stacking process. Liquids, by contrast, are found at intermediate pressures and temperatures. The temperature is high enough to impart enough kinetic energy to prevent solid formation and the pressure is high enough to prevent the liquid from becoming a gas. Finally, a gas forms at low pressures and high temperatures. The high level of kinetic energy prevents molecules from associating with one another.Materials can undergo processes called phase transitions, meaning they can transition from one phase to another. The transition from a solid to a liquid is called melting, while the reverse transition is called freezing. Vaporization occurs when a liquid becomes a gas, while condensation occurs when a gas becomes a liquid. Finally, in a process called sublimation, a solid can directly become a gas without passing through a liquid phase. Additionally, when a gas directly becomes a solid, this is known as deposition.Q.According to the figure, the material represented by area three is in what phase?

Chemists can model how solids, liquids, and gases behave at different temperatures and pressures with a graph called a phase diagram. When the pressure and temperature are simultaneously known, a scientist can predict whether the material will be in a specific state. The diagram is divided into sections depending on the phase and the lines between sections represent phase transitions occurring between two or more separate phases.In general, solids of neatly stacked molecules exist when temperatures are low and pressures are intermediate. These values decrease the kinetic energy of the molecules enough to allow for attractive forces to begin the stacking process. Liquids, by contrast, are found at intermediate pressures and temperatures. The temperature is high enough to impart enough kinetic energy to prevent solid formation and the pressure is high enough to prevent the liquid from becoming a gas. Finally, a gas forms at low pressures and high temperatures. The high level of kinetic energy prevents molecules from associating with one another.Materials can undergo processes called phase transitions, meaning they can transition from one phase to another. The transition from a solid to a liquid is called melting, while the reverse transition is called freezing. Vaporization occurs when a liquid becomes a gas, while condensation occurs when a gas becomes a liquid. Finally, in a process called sublimation, a solid can directly become a gas without passing through a liquid phase. Additionally, when a gas directly becomes a solid, this is known as deposition.Q.According to the figure, the material represented by Area 1 is in what phase?

Chemists can model how solids, liquids, and gases behave at different temperatures and pressures with a graph called a phase diagram. When the pressure and temperature are simultaneously known, a scientist can predict whether the material will be in a specific state. The diagram is divided into sections depending on the phase and the lines between sections represent phase transitions occurring between two or more separate phases.In general, solids of neatly stacked molecules exist when temperatures are low and pressures are intermediate. These values decrease the kinetic energy of the molecules enough to allow for attractive forces to begin the stacking process. Liquids, by contrast, are found at intermediate pressures and temperatures. The temperature is high enough to impart enough kinetic energy to prevent solid formation and the pressure is high enough to prevent the liquid from becoming a gas. Finally, a gas forms at low pressures and high temperatures. The high level of kinetic energy prevents molecules from associating with one another.Materials can undergo processes called phase transitions, meaning they can transition from one phase to another. The transition from a solid to a liquid is called melting, while the reverse transition is called freezing. Vaporization occurs when a liquid becomes a gas, while condensation occurs when a gas becomes a liquid. Finally, in a process called sublimation, a solid can directly become a gas without passing through a liquid phase. Additionally, when a gas directly becomes a solid, this is known as deposition.Q. According to the figure, the material represented by area two is in what phase?

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The value of a in van der Waal equation is _________ /dependent on _________.a)pressureb)temperaturec)pressure and temperatured)independent of pressure and temperatureCorrect answer is option 'D'. Can you explain this answer?
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