Chemistry Exam  >  Chemistry Questions  >  Probability of finding free particle inside t... Start Learning for Free
Probability of finding free particle inside the left half of a 1-D box of length L?
Most Upvoted Answer
Probability of finding free particle inside the left half of a 1-D box...
Probability of finding a free particle inside the left half of a 1-D box of length L

In quantum mechanics, the probability of finding a particle in a certain region is given by the square of the wavefunction. For a free particle in a 1-D box, the wavefunction can be represented by a sine or cosine function. Let's assume that the particle is in the ground state, which corresponds to the lowest energy state of the system.

1. Ground state wavefunction

The ground state wavefunction for a particle in a 1-D box of length L can be represented as:

ψ(x) = √(2/L) * sin((π/L) * x)

where x is the position of the particle inside the box, and L is the length of the box.

2. Probability density

The probability density, |ψ(x)|^2, gives the probability of finding the particle at a particular position x. For a free particle in the ground state, the probability density is:

|ψ(x)|^2 = (2/L) * sin^2((π/L) * x)

3. Finding the probability within the left half of the box

To find the probability of finding the particle inside the left half of the box, we need to integrate the probability density function from x = 0 to x = L/2. The integral is given by:

P = ∫[0 to L/2] |ψ(x)|^2 dx

P = ∫[0 to L/2] (2/L) * sin^2((π/L) * x) dx

Simplifying the integral, we have:

P = (2/L) * ∫[0 to L/2] sin^2((π/L) * x) dx

4. Solving the integral

Using a trigonometric identity, sin^2(θ) = (1/2) * (1 - cos(2θ)), we can rewrite the integral as:

P = (2/L) * ∫[0 to L/2] (1/2) * (1 - cos((2π/L) * x)) dx

Simplifying further, we have:

P = (1/L) * [x - (L/(2π)) * sin((2π/L) * x)] evaluated from 0 to L/2

P = (1/L) * (L/2 - (L/(2π)) * sin(π)) - (1/L) * (0 - (L/(2π)) * sin(0))

P = (1/2) - (1/π) * sin(π)

Since sin(π) = 0, the probability simplifies to:

P = (1/2) - 0

P = 1/2

5. Conclusion

Therefore, the probability of finding a free particle inside the left half of a 1-D box of length L is 1/2. This means that there is an equal chance of finding the particle on either side of the box.
Explore Courses for Chemistry exam
Probability of finding free particle inside the left half of a 1-D box of length L?
Question Description
Probability of finding free particle inside the left half of a 1-D box of length L? for Chemistry 2024 is part of Chemistry preparation. The Question and answers have been prepared according to the Chemistry exam syllabus. Information about Probability of finding free particle inside the left half of a 1-D box of length L? covers all topics & solutions for Chemistry 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Probability of finding free particle inside the left half of a 1-D box of length L?.
Solutions for Probability of finding free particle inside the left half of a 1-D box of length L? in English & in Hindi are available as part of our courses for Chemistry. Download more important topics, notes, lectures and mock test series for Chemistry Exam by signing up for free.
Here you can find the meaning of Probability of finding free particle inside the left half of a 1-D box of length L? defined & explained in the simplest way possible. Besides giving the explanation of Probability of finding free particle inside the left half of a 1-D box of length L?, a detailed solution for Probability of finding free particle inside the left half of a 1-D box of length L? has been provided alongside types of Probability of finding free particle inside the left half of a 1-D box of length L? theory, EduRev gives you an ample number of questions to practice Probability of finding free particle inside the left half of a 1-D box of length L? tests, examples and also practice Chemistry tests.
Explore Courses for Chemistry exam
Signup for Free!
Signup to see your scores go up within 7 days! Learn & Practice with 1000+ FREE Notes, Videos & Tests.
10M+ students study on EduRev