Lewis concept does explain the behaviour of __________a)basesb)saltsc)...
The major limitations of the Lewis concept is that it does not explain the behaviour of protonic acids such as hydrochloric acid, sulphuric acid and nitric acid. It also does not predict the magnitude of the relative strength of acids and bases.
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Lewis concept does explain the behaviour of __________a)basesb)saltsc)...
The Lewis concept of acids and bases, proposed by Gilbert N. Lewis in 1923, provides a broader understanding of acid-base behavior beyond the traditional Arrhenius and Brønsted-Lowry theories. According to the Lewis concept, an acid is defined as a substance that can accept a pair of electrons, while a base is a substance that can donate a pair of electrons. This concept helps explain the behavior of protonic acids, which are substances that can donate a proton (H+) in a chemical reaction.
Explanation:
- The Lewis concept of acids and bases is a more inclusive theory that goes beyond the limitations of the Arrhenius and Brønsted-Lowry theories. It focuses on the electron-pair transfer in chemical reactions.
- According to the Lewis concept, an acid is a substance that can accept a pair of electrons to form a coordinate covalent bond. This means that acids are electron pair acceptors.
- On the other hand, a base is a substance that can donate a pair of electrons to form a coordinate covalent bond. Bases are electron pair donors.
- Protonic acids are substances that can donate a proton (H+) in a chemical reaction. In the Lewis concept, this behavior can be explained by the fact that the proton can accept a pair of electrons from a base, forming a coordinate covalent bond.
- When a protonic acid donates a proton, it becomes a conjugate base, which is the species that remains after the acid has donated a proton.
- In the Lewis concept, amphoteric substances are substances that can act as both acids and bases, as they can both accept and donate a pair of electrons. This behavior is explained by their ability to form coordinate covalent bonds with other substances.
- Lewis acids and bases can also form complexes with each other, where the Lewis acid accepts a pair of electrons from the Lewis base, forming a coordinate covalent bond.
- Salt is not specifically explained by the Lewis concept of acids and bases, as it refers to the product of a neutralization reaction between an acid and a base, according to the Arrhenius or Brønsted-Lowry theories.
In summary, the Lewis concept of acids and bases provides a more comprehensive explanation of acid-base behavior, including the behavior of protonic acids and amphoteric substances. It focuses on the transfer of electron pairs in chemical reactions, allowing for a broader understanding of acid-base interactions.