UGC NET Exam > UGC NET Questions > For the following outer sphere electron trans...
Start Learning for Free
For the following outer sphere electron transfer reactions,
The rate constants are 10-6 M-1S-1 and 10-6 M-1S-1 respectively. The difference in rate constants is due to
The rate constants are 10-6 M-1S-1 and 10-6 M-1S-1 respectively. The difference in rate constants is due to
- a)A change from high spin to low spin in Co* and high spin to low spin in Ru*
- b)A change from high spin to low spin in Co* and low spin to high spin in Ru*
- c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*
- d)A change from low spin to high spin in Co* and high spin to low spin in Ru*
Correct answer is option 'C'. Can you explain this answer?
| FREE This question is part of | Download PDF Attempt this Test |
Most Upvoted Answer
For the following outer sphere electron transfer reactions,The rate co...
For the given reaction
[Co(NH3)6]2+ + [Co*(NH3)6]3+ → [Co(NH3)6]3+ + [Co*(NH3)6]2+
[Co(NH3)6]2+ + [Co*(NH3)6]3+ → [Co(NH3)6]3+ + [Co*(NH3)6]2+
- As both the reactants are kinetically inert and the left or right-hand side of the reaction are identical, the electron transfer reaction takes place by self-exchange outer sphere mechanism.
- Self-exchange electron transfer reaction which involves the greater change in Metal-Ligand bond length from one oxidation state to another slower will be the rate of electron transfer reaction.
- Now, the electron transfer reaction between [Co(NH3 )6]2+ and [*Co(NH3 )6]3+ not only involves a change in M-L bond length but also involves a change in spin state.
- [Co(NH3 )6]2+ is high spin d7 (t52ge2g) and [Co*(NH3 )6]3+ is low spin d6 (t62ge0g). Transfer of an electron between the exited state leads to the configuration of t52ge1g for [*Co(NH3 )6]3+ and t62ge1g for [Co(NH3 )6]2+.
- In this case, the spin states change from low spin to high spin in Co*.
- In such cases the activation energy for the electron transfer is high and the rate of the reaction is very slow and the rate constant of the reaction is 10-6 M-1S-1.
Also, for the given reaction
[Ru(NH3)6]2+ + [Ru*(NH3)6]3+ → [Ru(NH3)6]3+ + [Ru*(NH3)6]2+
[Ru(NH3)6]2+ + [Ru*(NH3)6]3+ → [Ru(NH3)6]3+ + [Ru*(NH3)6]2+
- The electron transfer reaction between [Ru(NH3)6]2+ and [Ru*(NH3)6]3+ only involves a change in M-L bond length.
- [Ru(NH3)6]2+ is low spin d6 (t62ge0g) and [Ru*(NH3)6]3+ is low spin d5 (t52ge0g). Transfer of an electron between the exited state leads to the configuration of t52ge0g for [Ru(NH3)6]3+ and t62ge0g for [Ru*(NH3 )6]2+.
- Thus, there is no change in the spin state involved and the low spin state remains unchanged in Ru*.
- In such cases the activation energy for the electron transfer is high and the rate of the reaction is very slow and the rate constant of the reaction is 10-6 M-1S-1.
Hence, for the two following outer sphere electron transfer reactions the difference in rate constants is due to a change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*.
Attention UGC NET Students!
To make sure you are not studying endlessly, EduRev has designed UGC NET study material, with Structured Courses, Videos, & Test Series. Plus get personalized analysis, doubt solving and improvement plans to achieve a great score in UGC NET.
|
Explore Courses for UGC NET exam
|
|
Top Courses for UGC NETView all
For the following outer sphere electron transfer reactions,The rate constants are 10-6M-1S-1and10-6M-1S-1respectively. The difference in rate constants is due toa)A change from high spin to low spin in Co* and high spin to low spin in Ru*b)A change from high spin to low spin in Co* and low spin to high spin in Ru*c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*d)A change from low spin tohighspin in Co* and high spin to low spin in Ru*Correct answer is option 'C'. Can you explain this answer?
Question Description
For the following outer sphere electron transfer reactions,The rate constants are 10-6M-1S-1and10-6M-1S-1respectively. The difference in rate constants is due toa)A change from high spin to low spin in Co* and high spin to low spin in Ru*b)A change from high spin to low spin in Co* and low spin to high spin in Ru*c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*d)A change from low spin tohighspin in Co* and high spin to low spin in Ru*Correct answer is option 'C'. Can you explain this answer? for UGC NET 2024 is part of UGC NET preparation. The Question and answers have been prepared according to the UGC NET exam syllabus. Information about For the following outer sphere electron transfer reactions,The rate constants are 10-6M-1S-1and10-6M-1S-1respectively. The difference in rate constants is due toa)A change from high spin to low spin in Co* and high spin to low spin in Ru*b)A change from high spin to low spin in Co* and low spin to high spin in Ru*c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*d)A change from low spin tohighspin in Co* and high spin to low spin in Ru*Correct answer is option 'C'. Can you explain this answer? covers all topics & solutions for UGC NET 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for For the following outer sphere electron transfer reactions,The rate constants are 10-6M-1S-1and10-6M-1S-1respectively. The difference in rate constants is due toa)A change from high spin to low spin in Co* and high spin to low spin in Ru*b)A change from high spin to low spin in Co* and low spin to high spin in Ru*c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*d)A change from low spin tohighspin in Co* and high spin to low spin in Ru*Correct answer is option 'C'. Can you explain this answer?.
For the following outer sphere electron transfer reactions,The rate constants are 10-6M-1S-1and10-6M-1S-1respectively. The difference in rate constants is due toa)A change from high spin to low spin in Co* and high spin to low spin in Ru*b)A change from high spin to low spin in Co* and low spin to high spin in Ru*c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*d)A change from low spin tohighspin in Co* and high spin to low spin in Ru*Correct answer is option 'C'. Can you explain this answer? for UGC NET 2024 is part of UGC NET preparation. The Question and answers have been prepared according to the UGC NET exam syllabus. Information about For the following outer sphere electron transfer reactions,The rate constants are 10-6M-1S-1and10-6M-1S-1respectively. The difference in rate constants is due toa)A change from high spin to low spin in Co* and high spin to low spin in Ru*b)A change from high spin to low spin in Co* and low spin to high spin in Ru*c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*d)A change from low spin tohighspin in Co* and high spin to low spin in Ru*Correct answer is option 'C'. Can you explain this answer? covers all topics & solutions for UGC NET 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for For the following outer sphere electron transfer reactions,The rate constants are 10-6M-1S-1and10-6M-1S-1respectively. The difference in rate constants is due toa)A change from high spin to low spin in Co* and high spin to low spin in Ru*b)A change from high spin to low spin in Co* and low spin to high spin in Ru*c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*d)A change from low spin tohighspin in Co* and high spin to low spin in Ru*Correct answer is option 'C'. Can you explain this answer?.
Solutions for For the following outer sphere electron transfer reactions,The rate constants are 10-6M-1S-1and10-6M-1S-1respectively. The difference in rate constants is due toa)A change from high spin to low spin in Co* and high spin to low spin in Ru*b)A change from high spin to low spin in Co* and low spin to high spin in Ru*c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*d)A change from low spin tohighspin in Co* and high spin to low spin in Ru*Correct answer is option 'C'. Can you explain this answer? in English & in Hindi are available as part of our courses for UGC NET.
Download more important topics, notes, lectures and mock test series for UGC NET Exam by signing up for free.
Here you can find the meaning of For the following outer sphere electron transfer reactions,The rate constants are 10-6M-1S-1and10-6M-1S-1respectively. The difference in rate constants is due toa)A change from high spin to low spin in Co* and high spin to low spin in Ru*b)A change from high spin to low spin in Co* and low spin to high spin in Ru*c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*d)A change from low spin tohighspin in Co* and high spin to low spin in Ru*Correct answer is option 'C'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of
For the following outer sphere electron transfer reactions,The rate constants are 10-6M-1S-1and10-6M-1S-1respectively. The difference in rate constants is due toa)A change from high spin to low spin in Co* and high spin to low spin in Ru*b)A change from high spin to low spin in Co* and low spin to high spin in Ru*c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*d)A change from low spin tohighspin in Co* and high spin to low spin in Ru*Correct answer is option 'C'. Can you explain this answer?, a detailed solution for For the following outer sphere electron transfer reactions,The rate constants are 10-6M-1S-1and10-6M-1S-1respectively. The difference in rate constants is due toa)A change from high spin to low spin in Co* and high spin to low spin in Ru*b)A change from high spin to low spin in Co* and low spin to high spin in Ru*c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*d)A change from low spin tohighspin in Co* and high spin to low spin in Ru*Correct answer is option 'C'. Can you explain this answer? has been provided alongside types of For the following outer sphere electron transfer reactions,The rate constants are 10-6M-1S-1and10-6M-1S-1respectively. The difference in rate constants is due toa)A change from high spin to low spin in Co* and high spin to low spin in Ru*b)A change from high spin to low spin in Co* and low spin to high spin in Ru*c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*d)A change from low spin tohighspin in Co* and high spin to low spin in Ru*Correct answer is option 'C'. Can you explain this answer? theory, EduRev gives you an
ample number of questions to practice For the following outer sphere electron transfer reactions,The rate constants are 10-6M-1S-1and10-6M-1S-1respectively. The difference in rate constants is due toa)A change from high spin to low spin in Co* and high spin to low spin in Ru*b)A change from high spin to low spin in Co* and low spin to high spin in Ru*c)A change from low spin to high spin in Co* and the low spin state remains unchanged in Ru*d)A change from low spin tohighspin in Co* and high spin to low spin in Ru*Correct answer is option 'C'. Can you explain this answer? tests, examples and also practice UGC NET tests.
|
|
Explore Courses for UGC NET exam
|
|
Suggested Free Tests
Signup for Free!
Signup to see your scores go up within 7 days! Learn & Practice with 1000+ FREE Notes, Videos & Tests.
|
© EduRev
|
Education Revolution
|
Follow Us
|
Signup to see your scores
go up within 7 days!
Access 1000+ FREE Docs, Videos and Tests
Takes less than 10 seconds to signup