The correct form for a simle Langmuir isotherm isa)ø =Kpb)&osla...
- Adsorption isotherms: it illustrate the connection between the degree of adsorption (denoted as θ) and the concentration or pressure of the adsorbate (denoted as p) at a specific temperature. The Langmuir isotherm model is commonly applied to represent this relationship, especially when describing the adsorption of a monolayer of molecules on a surface.
- Equilibrium Constant (Kp): The equilibrium constant (Kp) in the Langmuir isotherm equation reveals the balance between the rate of adsorption and the rate of desorption. Kp relies on factors such as the adsorption energy and the number of available sites on the surface. A higher Kp indicates a more significant adsorption tendency.
- Fractional Surface Coverage (θ): The symbol θ represents the fractional surface coverage, signifying the proportion of available adsorption sites that are occupied by adsorbate molecules. It ranges from 0 (indicating no adsorption) to 1 (indicating complete coverage by a monolayer). The Langmuir isotherm equation predicts how θ changes with variations in p.
The Langmuir isotherm is a fundamental model used to describe the adsorption of molecules onto a surface, such as in the case of gas adsorption on a solid surface. The correct form of the Langmuir isotherm equation is as follows:
ø = Kp/(1+Kp)
θ represents the fractional surface coverage or the fraction of sites occupied by adsorbed molecules.
Kp is the equilibrium constant, which is related to the adsorption energy and the number of available sites.
p is the pressure of the gas or the concentration of the adsorbate in the gas phase.
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The correct form for a simle Langmuir isotherm isa)ø =Kpb)&osla...
Explanation:
Langmuir Isotherm Equation:
The Langmuir isotherm is a model that describes the adsorption of molecules onto a solid surface. The Langmuir isotherm equation is given by:
\[
\theta = \frac{K \cdot p}{1 + K \cdot p}
\]
where:
- \(\theta\) is the fractional coverage of the surface
- \(K\) is the Langmuir constant
- \(p\) is the pressure of the gas phase
Interpretation of Langmuir Isotherm Equation:
- The Langmuir isotherm equation represents a monolayer adsorption process where the adsorbate molecules form a single layer on the surface.
- As the pressure of the gas phase increases, the fractional coverage also increases, but it reaches a saturation point at higher pressures.
Correct Answer:
The correct form for a simple Langmuir isotherm is:
\(\theta = \frac{K \cdot p}{1 + K \cdot p}\)
Explanation of Correct Answer:
- The correct answer is option 'C', which is \(\theta = \frac{K \cdot p}{1 + K \cdot p}\).
- This equation represents the Langmuir isotherm in a simple form where the fractional coverage (\(\theta\)) is directly proportional to the pressure of the gas phase (\(p\)).
- The Langmuir constant (\(K\)) in the denominator accounts for the saturation behavior of the adsorption process.
In conclusion, the Langmuir isotherm equation is a fundamental model in surface chemistry that describes the adsorption behavior of molecules on a solid surface. The correct form of the Langmuir isotherm equation is crucial for understanding and predicting adsorption processes in various applications.