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Consider the following statements about the Oxo‐process:
A. The reaction is first order with respect to olefin.
B. The rate is faster for terminal olefins compared to internal olefins.
C. The rate is faster for internal olefins compared to terminal olefins.
D. Excess of CO inhibits the reaction.
The correct statements are
  • a)
    A, B and D only
  • b)
    C and D only 
  • c)
    A and B only
  • d)
    A and D only
Correct answer is option 'A'. Can you explain this answer?
Most Upvoted Answer
Consider the following statements about the Oxoprocess:A. The reaction...
Statement-A: The reaction is first order with respect to olefin.
  • The rate law for the oxo process is,

  • From the above rate law, we can conclude that the reaction is first order with respect to olefin.
  • Thus, statement A is correct.
Statement-B: The rate is faster for terminal olefins compared to internal olefins.
  • In the context of the Oxo Process, terminal olefins (olefins with a double bond at the end of the carbon chain) tend to react faster compared to internal olefins (olefins with a double bond somewhere in the middle of the carbon chain). This can be attributed to Steric Effects.
  • Thus, statement B is correct.
Statement-C:  The rate is faster for internal olefins compared to terminal olefins.
  • As in the oxo process, terminal olefins tend to react faster compared to internal olefins, statement C is incorrect.
Statement-D: Excess of CO inhibits the reaction.
  • With the increase in CO pressure, the reaction rate decreases & high ratio of linear to branched product are formed.
  • At extreme pressure of CO, the reaction rate becomes very low and it inhibits the reaction.
  • Thus, statement D is correct.
Hence, the correct statements are A, B, and D only.
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Community Answer
Consider the following statements about the Oxoprocess:A. The reaction...
Explanation:

First Order Reaction:
- The statement A is correct as the Oxoprocess is a first order reaction with respect to olefin. This means that the rate of the reaction is directly proportional to the concentration of the olefin.

Rate of Terminal vs Internal Olefins:
- Statement B is correct as the rate of the Oxoprocess is generally faster for terminal olefins compared to internal olefins. This is due to the higher reactivity of terminal olefins.

Excess of CO Inhibits the Reaction:
- Statement D is correct as an excess of carbon monoxide (CO) can inhibit the Oxoprocess reaction. CO can act as a competitive inhibitor, reducing the rate of the reaction by interfering with the binding of olefins to the catalyst.
Therefore, the correct statements are A and D.
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Consider the following statements about the Oxoprocess:A. The reaction is first order with respect to olefin.B. The rate is faster for terminal olefins compared to internal olefins.C. The rate is faster for internal olefins compared to terminal olefins.D. Excess of CO inhibits the reaction.The correct statements area)A, B and D onlyb)C and D onlyc)A and B onlyd)A and D onlyCorrect answer is option 'A'. Can you explain this answer?
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Consider the following statements about the Oxoprocess:A. The reaction is first order with respect to olefin.B. The rate is faster for terminal olefins compared to internal olefins.C. The rate is faster for internal olefins compared to terminal olefins.D. Excess of CO inhibits the reaction.The correct statements area)A, B and D onlyb)C and D onlyc)A and B onlyd)A and D onlyCorrect answer is option 'A'. Can you explain this answer? for UGC NET 2024 is part of UGC NET preparation. The Question and answers have been prepared according to the UGC NET exam syllabus. Information about Consider the following statements about the Oxoprocess:A. The reaction is first order with respect to olefin.B. The rate is faster for terminal olefins compared to internal olefins.C. The rate is faster for internal olefins compared to terminal olefins.D. Excess of CO inhibits the reaction.The correct statements area)A, B and D onlyb)C and D onlyc)A and B onlyd)A and D onlyCorrect answer is option 'A'. Can you explain this answer? covers all topics & solutions for UGC NET 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Consider the following statements about the Oxoprocess:A. The reaction is first order with respect to olefin.B. The rate is faster for terminal olefins compared to internal olefins.C. The rate is faster for internal olefins compared to terminal olefins.D. Excess of CO inhibits the reaction.The correct statements area)A, B and D onlyb)C and D onlyc)A and B onlyd)A and D onlyCorrect answer is option 'A'. Can you explain this answer?.
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