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Can you explain the answer of this question below:
The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due to
  • A:
    Ionic nature of lithium fluoride
  • B:
    High lattice enthalpy
  • C:
    High hydration enthalpy for lithium ion.
  • D:
    Low ionisation enthalpy of lithium atom
The answer is b.
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Can you explain the answer of this question below:The solubility of me...
K2O,    KO2,  K2O2
Rb2O,   RbO2,   Rb2O2
Na, Li from normal oxide
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Most Upvoted Answer
Can you explain the answer of this question below:The solubility of me...
(b) Due to small size of Li^+ and F^- ions, lattice enthalpy is much higher than hydration enthalpy and hence LiF is least soluble among alkali metal fluorides.
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Can you explain the answer of this question below:The solubility of me...
Understanding the Solubility of LiF
The solubility of lithium fluoride (LiF) in water is influenced by multiple factors, with the most significant being its lattice enthalpy. Let's explore why option B is the correct answer.
What is Lattice Enthalpy?
- Lattice enthalpy refers to the energy required to separate one mole of an ionic compound into its gaseous ions.
- A high lattice enthalpy indicates strong ionic bonds between the ions in the solid state, making them less likely to dissolve in water.
Why LiF has High Lattice Enthalpy
- Lithium fluoride has a small ionic size due to the lithium ion (Li+), which creates a strong electrostatic attraction between Li+ and F- ions.
- This strong attraction results in a high lattice enthalpy, making it energetically unfavorable for LiF to dissociate in water.
Hydration Enthalpy vs. Lattice Enthalpy
- Although Li+ has a high hydration enthalpy, which means it can interact favorably with water molecules, this factor alone is not enough to overcome the high lattice enthalpy of LiF.
- In the case of LiF, the high lattice enthalpy outweighs the favorable hydration enthalpy, leading to its low solubility.
Conclusion
- Therefore, the solubility of lithium fluoride in water is primarily affected by its high lattice enthalpy, which makes it less soluble compared to other alkali metal fluorides.
- The other options (A, C, and D) do not significantly contribute to the low solubility of LiF, confirming that option B is indeed the correct choice.
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Can you explain the answer of this question below:The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due toA:Ionic nature of lithium fluorideB:High lattice enthalpyC:High hydration enthalpy for lithium ion.D:Low ionisation enthalpy of lithium atomThe answer is b. for Class 11 2025 is part of Class 11 preparation. The Question and answers have been prepared according to the Class 11 exam syllabus. Information about Can you explain the answer of this question below:The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due toA:Ionic nature of lithium fluorideB:High lattice enthalpyC:High hydration enthalpy for lithium ion.D:Low ionisation enthalpy of lithium atomThe answer is b. covers all topics & solutions for Class 11 2025 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Can you explain the answer of this question below:The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due toA:Ionic nature of lithium fluorideB:High lattice enthalpyC:High hydration enthalpy for lithium ion.D:Low ionisation enthalpy of lithium atomThe answer is b..
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