For the equilibrium 2NOCl(\rho)\rightleftharpoons2NO(g)+Cl_{2}(g) the ...
Equilibrium Expression
The equilibrium expression for the given reaction is:
Kc = [NO]2[Cl2]/[NOCl]2
where [NO], [Cl2], and [NOCl] represent the molar concentrations of NO, Cl2, and NOCl, respectively.
Conversion from Kc to Kp
To calculate the value of Kp at 1069 K, we need to convert the equilibrium constant Kc into Kp using the following equation:
Kp = Kc * (RT)Δn
where R is the ideal gas constant (0.0821 L·atm/(K·mol)), T is the temperature in Kelvin (1069 K), and Δn is the change in the number of moles of gas.
Calculating Δn
In the given reaction, the number of moles of gas on the product side is 2 (2 moles of NO) + 1 (1 mole of Cl2) = 3 moles. The number of moles of gas on the reactant side is 2 (2 moles of NOCl). Therefore, Δn = 3 - 2 = 1.
Calculating Kp
Using the equation Kp = Kc * (RT)Δn, we can calculate Kp as follows:
Kp = 3.75 × 10-6 * (0.0821 L·atm/(K·mol) * 1069 K)1
Simplifying the equation:
Kp = 3.75 × 10-6 * (88.9649 L·atm/(mol·K))
Kp ≈ 3.34 × 10-4 atm
Explanation
The equilibrium constant Kc is a measure of the concentrations of the reactants and products at equilibrium. It is defined as the ratio of the product concentrations to the reactant concentrations, with each concentration raised to the power of its stoichiometric coefficient.
To calculate the equilibrium constant Kp, we need to convert Kc using the equation Kp = Kc * (RT)Δn. The value of Kp will depend on the temperature and the change in the number of moles of gas (Δn) between the reactants and products.
In this case, the value of Kp at 1069 K is approximately 3.34 × 10-4 atm. This means that at equilibrium, the concentration of the products
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