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In the complex PtCl4 . 5NH3 if coordination number of platinum is 6, number of chloride ions precipitated by adding AgNO3 are

    Correct answer is '3'. Can you explain this answer?
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    In the complex PtCl4 .5NH3 if coordination number of platinum is 6, nu...
    Coordination number of platinum is 6.
    ∴ Number of chloride ions precipitated by adding AgCI are 3.
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    In the complex PtCl4 .5NH3 if coordination number of platinum is 6, nu...
    Solution:

    Coordination number of the complex PtCl4 .5NH3 is given as 6. This means that there are 6 ligands attached to the central metal ion (Platinum) in the complex.

    The formula of the complex is PtCl4 .5NH3 which means there are 4 chloride ions and 5 ammonia molecules attached to the central platinum ion.

    When AgNO3 is added to the solution of the complex, Ag+ ions will react with Cl- ions to form insoluble AgCl precipitate. The number of chloride ions that will be precipitated can be calculated as follows:

    - The charge on the central platinum ion is +4 since there are 4 chloride ions attached to it.
    - The coordination number of the platinum ion is 6, which means that there are 6 ligands attached to it.
    - Since each ammonia molecule is a neutral ligand, the total charge contributed by them is zero.
    - Therefore, the total charge contributed by the 6 ligands is -4.
    - This means that there are 4 negative charges on the complex.
    - When AgNO3 is added to the solution, Ag+ ions will react with Cl- ions to form insoluble AgCl precipitate.
    - Since the complex has 4 Cl- ions, only 3 of them will react with Ag+ ions to form AgCl precipitate.
    - The remaining chloride ion will stay in the solution.

    Therefore, the number of chloride ions precipitated by adding AgNO3 to the solution of PtCl4 .5NH3 is 3.
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    In the complex PtCl4 .5NH3 if coordination number of platinum is 6, nu...
    Pt5NH3Cl. 3Cl+ AgCl ,,pt5Nh3Cl is a complex which is not ionisable and coordination no is 6 and ammonial all the molecules will get bonded to pt only one place can be occupied by the cl rest 3 will be present free and can get precipitated by adding AgCl
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    In the complex PtCl4 .5NH3 if coordination number of platinum is 6, number of chloride ions precipitated by adding AgNO3areCorrect answer is '3'. Can you explain this answer?
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