For which of the following parameters the structural isomers C2H5OH an...
Vapor density = Molecular weight/2
As both the compounds have same molecular weights, both will have the same vapour density. Hence, gaseous density of both ethanol and dimethyl ether would be same under identical conditions of temperature and pressure. The rest of these three properties; Vapour pressure, boiling point and heat of vaporization will differ as ethanol has hydrogen bonding whereas ether does not.
View all questions of this test
For which of the following parameters the structural isomers C2H5OH an...
Vapor density = Molecular weight/2
As both the compounds have same molecular weights, both will have the same vapour density. Hence, gaseous density of both ethanol and dimethyl ether would be same under identical conditions of temperature and pressure. The rest of these three properties; Vapour pressure, boiling point and heat of vaporization will differ as ethanol has hydrogen bonding whereas ether does not.
For which of the following parameters the structural isomers C2H5OH an...
Understanding Structural Isomers
Structural isomers, like C2H5OH (ethanol) and CH3OCH3 (dimethyl ether), have the same molecular formula but different structures and properties. Analyzing their physical properties helps determine which parameters they share.
Comparison of Physical Properties
- Heat of Vaporization
- Different molecular structures lead to varying intermolecular forces.
- Ethanol has hydrogen bonding, while dimethyl ether has dipole-dipole interactions.
- Thus, their heat of vaporization differs.
- Vapor Pressure at the Same Temperature
- Vapor pressure is influenced by intermolecular forces.
- Ethanol's stronger hydrogen bonding results in lower vapor pressure compared to dimethyl ether.
- Therefore, they do not share the same vapor pressure.
- Boiling Points
- Boiling points depend on intermolecular attractions.
- Ethanol's hydrogen bonds cause a higher boiling point than dimethyl ether's weaker forces.
- Hence, their boiling points are different.
- Gaseous Densities at the Same Temperature and Pressure
- Density of gases is determined by the number of moles in a given volume.
- Both compounds have the same molecular formula (C2H6O) and thus the same molar mass.
- Under ideal gas conditions (same temperature and pressure), they will exhibit the same gaseous densities.
Conclusion
In summary, the only parameter for which C2H5OH and CH3OCH3 would have the same values is the gaseous densities at the same temperature and pressure. This is due to their identical molecular weights, despite their differing structures and physical properties.