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When [Ni(NH3)4] 2t is treated with conc, HCl two compounds A and B having the same formula Ni(NH), els are formed. 'A' reacts readily with Ag, C204 to give a white precipitate, whereas B does not. Identify A and B, explain the difference in reactivity towards Ag2204.?
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When [Ni(NH3)4] 2t is treated with conc, HCl two compounds A and B hav...
Identification of compounds A and B:
- Compound A is [Ni(NH3)3Cl]Cl
- Compound B is [Ni(NH3)4]Cl2
Explanation of reactivity towards Ag2C2O4:
- Compound A ([Ni(NH3)3Cl]Cl) reacts readily with Ag2C2O4 to give a white precipitate because it contains a chloride ligand (Cl-) which can be easily replaced by oxalate ions (C2O4^2-).
- On the other hand, compound B ([Ni(NH3)4]Cl2) does not react with Ag2C2O4 because it does not contain any chloride ligands that can be replaced by oxalate ions. The ammonia ligands in compound B are strong ligands and do not easily get replaced by other ligands.
Details of the reaction:
- When compound A is treated with Ag2C2O4, the silver ions (Ag+) react with the chloride ions (Cl-) in [Ni(NH3)3Cl]Cl to form a white precipitate of silver chloride (AgCl) and release the oxalate ions. The nickel ion remains in solution.
- However, compound B does not contain any chloride ions to react with silver ions. Therefore, there is no reaction between [Ni(NH3)4]Cl2 and Ag2C2O4, and no white precipitate is formed.
In conclusion, the difference in reactivity towards Ag2C2O4 between compounds A and B is due to the presence of chloride ligands in compound A, which can be easily replaced by oxalate ions, whereas compound B does not have any chloride ligands to react with silver ions.
- Compound A is [Ni(NH3)3Cl]Cl
- Compound B is [Ni(NH3)4]Cl2
Explanation of reactivity towards Ag2C2O4:
- Compound A ([Ni(NH3)3Cl]Cl) reacts readily with Ag2C2O4 to give a white precipitate because it contains a chloride ligand (Cl-) which can be easily replaced by oxalate ions (C2O4^2-).
- On the other hand, compound B ([Ni(NH3)4]Cl2) does not react with Ag2C2O4 because it does not contain any chloride ligands that can be replaced by oxalate ions. The ammonia ligands in compound B are strong ligands and do not easily get replaced by other ligands.
Details of the reaction:
- When compound A is treated with Ag2C2O4, the silver ions (Ag+) react with the chloride ions (Cl-) in [Ni(NH3)3Cl]Cl to form a white precipitate of silver chloride (AgCl) and release the oxalate ions. The nickel ion remains in solution.
- However, compound B does not contain any chloride ions to react with silver ions. Therefore, there is no reaction between [Ni(NH3)4]Cl2 and Ag2C2O4, and no white precipitate is formed.
In conclusion, the difference in reactivity towards Ag2C2O4 between compounds A and B is due to the presence of chloride ligands in compound A, which can be easily replaced by oxalate ions, whereas compound B does not have any chloride ligands to react with silver ions.
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When [Ni(NH3)4] 2t is treated with conc, HCl two compounds A and B having the same formula Ni(NH), els are formed. 'A' reacts readily with Ag, C204 to give a white precipitate, whereas B does not. Identify A and B, explain the difference in reactivity towards Ag2204.?
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When [Ni(NH3)4] 2t is treated with conc, HCl two compounds A and B having the same formula Ni(NH), els are formed. 'A' reacts readily with Ag, C204 to give a white precipitate, whereas B does not. Identify A and B, explain the difference in reactivity towards Ag2204.? for Chemistry 2024 is part of Chemistry preparation. The Question and answers have been prepared according to the Chemistry exam syllabus. Information about When [Ni(NH3)4] 2t is treated with conc, HCl two compounds A and B having the same formula Ni(NH), els are formed. 'A' reacts readily with Ag, C204 to give a white precipitate, whereas B does not. Identify A and B, explain the difference in reactivity towards Ag2204.? covers all topics & solutions for Chemistry 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for When [Ni(NH3)4] 2t is treated with conc, HCl two compounds A and B having the same formula Ni(NH), els are formed. 'A' reacts readily with Ag, C204 to give a white precipitate, whereas B does not. Identify A and B, explain the difference in reactivity towards Ag2204.?.
When [Ni(NH3)4] 2t is treated with conc, HCl two compounds A and B having the same formula Ni(NH), els are formed. 'A' reacts readily with Ag, C204 to give a white precipitate, whereas B does not. Identify A and B, explain the difference in reactivity towards Ag2204.? for Chemistry 2024 is part of Chemistry preparation. The Question and answers have been prepared according to the Chemistry exam syllabus. Information about When [Ni(NH3)4] 2t is treated with conc, HCl two compounds A and B having the same formula Ni(NH), els are formed. 'A' reacts readily with Ag, C204 to give a white precipitate, whereas B does not. Identify A and B, explain the difference in reactivity towards Ag2204.? covers all topics & solutions for Chemistry 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for When [Ni(NH3)4] 2t is treated with conc, HCl two compounds A and B having the same formula Ni(NH), els are formed. 'A' reacts readily with Ag, C204 to give a white precipitate, whereas B does not. Identify A and B, explain the difference in reactivity towards Ag2204.?.
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When [Ni(NH3)4] 2t is treated with conc, HCl two compounds A and B having the same formula Ni(NH), els are formed. 'A' reacts readily with Ag, C204 to give a white precipitate, whereas B does not. Identify A and B, explain the difference in reactivity towards Ag2204.?, a detailed solution for When [Ni(NH3)4] 2t is treated with conc, HCl two compounds A and B having the same formula Ni(NH), els are formed. 'A' reacts readily with Ag, C204 to give a white precipitate, whereas B does not. Identify A and B, explain the difference in reactivity towards Ag2204.? has been provided alongside types of When [Ni(NH3)4] 2t is treated with conc, HCl two compounds A and B having the same formula Ni(NH), els are formed. 'A' reacts readily with Ag, C204 to give a white precipitate, whereas B does not. Identify A and B, explain the difference in reactivity towards Ag2204.? theory, EduRev gives you an
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