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Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.
Assertion: Hoffmann's bromamide reaction is given by primary amines.
Reason: Primary amines are more basic than secondary amines.
  • a)
    If both A and R are true and R is the correct explanation of A
  • b)
    If both A and R are true but R is NOT the correct explanation of A
  • c)
    If A is true but R is false
  • d)
    If Both A and R is False
Correct answer is option 'D'. Can you explain this answer?
Verified Answer
Directions: In the following questions, A statement of Assertion (A) i...
The Hoffmann bromamide degradation reaction prepares primary amines by treating an amide with bromine in an aqueous or ethanolic sodium hydroxide solution. The resulting amine has one carbon atom less than the original amide.
Therefore, the assertion is incorrect because Hoffmann’s bromamide reaction involves amides rather than primary amines, even though the product is a primary amine.
Reason:
Primary amines are less basic than secondary amines because secondary amines have more electron-donating alkyl groups, which enhance their basicity. Thus, the reason statement is also incorrect.
Consequently, both the assertion and reason are wrong.
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Most Upvoted Answer
Directions: In the following questions, A statement of Assertion (A) i...
Understanding the Assertion and Reason
The question presents two statements regarding Hoffmann's bromamide reaction and the basicity of amines. Let's analyze both parts:
Assertion (A): Hoffmann's bromamide reaction is given by primary amines.
- Hoffmann's bromamide reaction specifically involves the conversion of primary amides to primary amines using bromine and a strong base, typically sodium hydroxide.
- However, this reaction does not occur with primary amines directly; it is the amides that participate in this reaction.
Reason (R): Primary amines are more basic than secondary amines.
- This statement is generally true. Primary amines tend to be more basic than secondary amines due to the presence of electron-donating alkyl groups, which enhance the availability of the lone pair of electrons on the nitrogen atom.
- That said, the basicity of amines is not the reason for the occurrence of Hoffmann's bromamide reaction.
Conclusion: Why the Correct Answer is D
- Both statements are not true in the context provided. The assertion is incorrect because Hoffmann's bromamide reaction involves primary amides, not primary amines.
- The reason, while true in a general sense regarding basicity, does not correlate to the assertion about Hoffmann's bromamide reaction.
Final Answer
Thus, the correct choice is option 'D' because both the assertion and the reason are false in the context of the question.
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Question Description
Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.Assertion: Hoffmanns bromamide reaction is given by primary amines.Reason: Primary amines are more basic than secondary amines.a)If both A and R are true and R is the correct explanation of Ab)If both A and R are true but R is NOT the correct explanation of Ac)If A is true but R is falsed)If Both A and R is FalseCorrect answer is option 'D'. Can you explain this answer? for NEET 2025 is part of NEET preparation. The Question and answers have been prepared according to the NEET exam syllabus. Information about Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.Assertion: Hoffmanns bromamide reaction is given by primary amines.Reason: Primary amines are more basic than secondary amines.a)If both A and R are true and R is the correct explanation of Ab)If both A and R are true but R is NOT the correct explanation of Ac)If A is true but R is falsed)If Both A and R is FalseCorrect answer is option 'D'. Can you explain this answer? covers all topics & solutions for NEET 2025 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.Assertion: Hoffmanns bromamide reaction is given by primary amines.Reason: Primary amines are more basic than secondary amines.a)If both A and R are true and R is the correct explanation of Ab)If both A and R are true but R is NOT the correct explanation of Ac)If A is true but R is falsed)If Both A and R is FalseCorrect answer is option 'D'. Can you explain this answer?.
Solutions for Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.Assertion: Hoffmanns bromamide reaction is given by primary amines.Reason: Primary amines are more basic than secondary amines.a)If both A and R are true and R is the correct explanation of Ab)If both A and R are true but R is NOT the correct explanation of Ac)If A is true but R is falsed)If Both A and R is FalseCorrect answer is option 'D'. Can you explain this answer? in English & in Hindi are available as part of our courses for NEET. Download more important topics, notes, lectures and mock test series for NEET Exam by signing up for free.
Here you can find the meaning of Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.Assertion: Hoffmanns bromamide reaction is given by primary amines.Reason: Primary amines are more basic than secondary amines.a)If both A and R are true and R is the correct explanation of Ab)If both A and R are true but R is NOT the correct explanation of Ac)If A is true but R is falsed)If Both A and R is FalseCorrect answer is option 'D'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.Assertion: Hoffmanns bromamide reaction is given by primary amines.Reason: Primary amines are more basic than secondary amines.a)If both A and R are true and R is the correct explanation of Ab)If both A and R are true but R is NOT the correct explanation of Ac)If A is true but R is falsed)If Both A and R is FalseCorrect answer is option 'D'. Can you explain this answer?, a detailed solution for Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.Assertion: Hoffmanns bromamide reaction is given by primary amines.Reason: Primary amines are more basic than secondary amines.a)If both A and R are true and R is the correct explanation of Ab)If both A and R are true but R is NOT the correct explanation of Ac)If A is true but R is falsed)If Both A and R is FalseCorrect answer is option 'D'. Can you explain this answer? has been provided alongside types of Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.Assertion: Hoffmanns bromamide reaction is given by primary amines.Reason: Primary amines are more basic than secondary amines.a)If both A and R are true and R is the correct explanation of Ab)If both A and R are true but R is NOT the correct explanation of Ac)If A is true but R is falsed)If Both A and R is FalseCorrect answer is option 'D'. Can you explain this answer? theory, EduRev gives you an ample number of questions to practice Directions: In the following questions, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.Assertion: Hoffmanns bromamide reaction is given by primary amines.Reason: Primary amines are more basic than secondary amines.a)If both A and R are true and R is the correct explanation of Ab)If both A and R are true but R is NOT the correct explanation of Ac)If A is true but R is falsed)If Both A and R is FalseCorrect answer is option 'D'. Can you explain this answer? tests, examples and also practice NEET tests.
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