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Arrange giving reasons the following bonds in order of there decreasing vibrational frequency
1)C-Cl 2)C-Br 3)C-C 4)C-O2 5)C-H 6)C-I?
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Arrange giving reasons the following bonds in order of there decreasin...
Factors Influencing Vibrational Frequency
Vibrational frequency of bonds is influenced by several factors including bond strength and mass of the bonded atoms. Generally, stronger bonds and lighter atoms lead to higher vibrational frequencies.
Bond Order and Strength
- C-H: Strong bond due to smaller size of hydrogen, resulting in high vibrational frequency.
- C-C: A single bond but stronger than halogen bonds due to the nature of carbon, leading to a relatively high frequency.
Mass of Atoms
- C-O2: The oxygen atom is lighter than halogens, resulting in a higher frequency than C-X bonds (X being a halogen).
- C-Cl, C-Br, C-I: As we move from Cl to I, the atomic mass increases, causing a decrease in vibrational frequency. C-Cl has a higher frequency than C-Br, and C-Br has a higher frequency than C-I due to their increasing bond lengths and decreasing bond strengths.
Order of Vibrational Frequency
Based on the above factors, the order of the bonds in decreasing vibrational frequency is:
1. C-H
2. C-O2
3. C-C
4. C-Cl
5. C-Br
6. C-I
Conclusion
In summary, the higher the bond strength and the lighter the atoms involved in the bond, the higher the vibrational frequency. C-H tops the list due to its strong bond and low mass, while C-I has the lowest frequency owing to its weaker bond and greater atomic mass.
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Arrange giving reasons the following bonds in order of there decreasing vibrational frequency 1)C-Cl 2)C-Br 3)C-C 4)C-O2 5)C-H 6)C-I?
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