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When benzamid is treated with POCl3, the product is:   [IIT 2004]
  • a)
    Benzonitrile
  • b)
    Aniline
  • c)
    Chlorobenzene
  • d)
    Benzylamine
Correct answer is option 'A'. Can you explain this answer?
Most Upvoted Answer
When benzamid is treated with POCl3, the product is: [IIT 2004]a)Benzo...
C6H5CONH2 + POCl3 —› C6H5CNOAs there`s no C6H5CNO (benzonitrile oxide) in the options above, the correct answer is C6H5CN (benzonitrile).
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Community Answer
When benzamid is treated with POCl3, the product is: [IIT 2004]a)Benzo...
Reaction:
When benzamide is treated with POCl3, it undergoes the Vilsmeier-Haack reaction to form benzonitrile.

Explanation:

1. Vilsmeier-Haack Reaction:
- The Vilsmeier-Haack reaction involves the conversion of an amide group into a nitrile group using POCl3.
- In this reaction, POCl3 acts as a dehydrating agent and reacts with the amide functional group to form an iminium ion intermediate.
- The iminium ion then undergoes hydrolysis to yield the nitrile product.

2. Formation of Benzonitrile:
- In the case of benzamide, the reaction with POCl3 leads to the formation of benzonitrile.
- The amide group in benzamide is converted into a nitrile group during the Vilsmeier-Haack reaction, resulting in the formation of benzonitrile as the product.
Therefore, the correct product formed when benzamide is treated with POCl3 is benzonitrile.
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When benzamid is treated with POCl3, the product is: [IIT 2004]a)Benzonitrileb)Anilinec)Chlorobenzened)BenzylamineCorrect answer is option 'A'. Can you explain this answer?
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