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 Nitro compounds are reduced to amines. The catalyst that is preferred is:
  • a)
    Sn + HCl
  • b)
    Fe + HCl
  • c)
    Ethanol
  • d)
    Mg + HCl
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
Nitro compounds are reduced to amines. The catalyst that is preferred ...
Fe + HCl is preferred due to the following reasons:
- Scrap iron i.e Fe is cheap and commercially easily available
- FeCl2 formed will get hydrolysed and release HCl, so, HCl which is required in the reaction will be produced by itself
- Hence only small amount of HCl is required to initiate the reaction.
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Most Upvoted Answer
Nitro compounds are reduced to amines. The catalyst that is preferred ...
Fe + HCl is preferred due to the following reasons:
- Scrap iron i.e Fe is cheap and commercially easily available
- FeCl2 formed will get hydrolysed and release HCl, so, HCl which is required in the reaction will be produced by itself
- Hence only small amount of HCl is required to initiate the reaction.
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Community Answer
Nitro compounds are reduced to amines. The catalyst that is preferred ...
In conversion of nitro compounds to amines ... Fe+ Steam is used in neutral medium...
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Read the passage given below and answer the following questions:Reductive alkylation is the term applied to the process of introducing alkyl groups into ammonia or a primary or secondary amine by means of an aldehyde or ketone in the presence of a reducing agent. The present discussion is limited to those reductive alkylations in which the reducing agent is hydrogen and a catalyst or "nascent" hydrogen, usually from a metalacid combination; most of these reductive alkylations have been carried out with hydrogen and a catalyst. The principal variation excluded is that in which the reducing agent is formic acid or one of its derivatives; this modification is known as the Leuckart reaction. The process of reductive alkylation of ammonia consists in the addition of ammonia to a carbonyl compound and reduction of the addition compound or its dehydration product. The reaction usually is carried out in ethanol solution when the reduction is to be effected catalytically:Since the primary amine is formed in the presence of the aldehyde it may react in the same way as ammonia, yielding an additional compound, a Schiff's base (RCH= NCH2R) and finally, a secondary amine. Similarly, the primary amine may react with the imine, forming an addition product which also is reduced to a secondary amine Finally, the secondary amine may react with either the aldehyde or the imine to give products which are reduced to tertiary amines.Similar reactions may occur when the carbonyl compound employed is a ketone.Q. The reaction of ammonia and its derivatives with aldehydes is called

Nitro compounds are reduced to amines. The catalyst that is preferred is:a)Sn + HClb)Fe + HClc)Ethanold)Mg + HClCorrect answer is option 'B'. Can you explain this answer?
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