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The major monobromination product which results when ethyl cyclohexane is subjected to free radical bromination, is

  • a)

  • b)

  • c)

  • d)

Correct answer is option 'D'. Can you explain this answer?
Verified Answer
The major monobromination product which results when ethyl cyclohexane...

Free radical bromination reaction is highly selective, occurs mainly at the carbon where most stable free radical is formed.
We know that the stability of free radical is in the order,
Tertiary radical > Secondary radical > Primary radical
In (a), (b) and (c), the bromination occurs at secondary carbon whereas in (d) the bromination occurs at tertiary carbon. Since, tertiary radicals are more stable than secondary radical the major product of monobromination of ethyl cyclohexane is (d).
The stability of tertiary radical is due to the higher number of α−Hygrogens which give more hyperconjugation effect than secondary.
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Most Upvoted Answer
The major monobromination product which results when ethyl cyclohexane...
It's a tertiary bromide . Br2 converts into Br+ Be because of free radical abstracts Br form new Br2 to continue the chain
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Community Answer
The major monobromination product which results when ethyl cyclohexane...
It's a tertiary bromide . Br2 converts into Br+ Be because of free radical abstracts Br form new Br2 to continue the chain
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