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 Molar conductivity for a compound AB is 145.0 Scm2mol-1 and for CB is 110.1 Scm2mol-1. Limiting molar conductivity for A+ is 73.5 Scm2mol-1. What is limiting molar conductivity for C+?
  • a)
    326.6 S cm2 mol-1
  • b)
    38.6 S cm2 mol-1
  • c)
    181.6 S cm2 mol-1
  • d)
    90.8 S cm2 mol-1
Correct answer is option 'B'. Can you explain this answer?
Most Upvoted Answer
Molar conductivity for a compound AB is 145.0 Scm2mol-1and for CB is 1...
Given:
Molar conductivity of AB = 145.0 Scm²mol⁻¹
Molar conductivity of CB = 110.1 Scm²mol⁻¹
Limiting molar conductivity of A = 73.5 Scm²mol⁻¹

To find: Limiting molar conductivity of C

Formula used:
Kohlrausch law of independent migration of ions states that the limiting molar conductivity of an electrolyte can be represented as the sum of the molar conductivity of its cation and anion, each multiplied by its own migration constant. That is,
Λ°(AB) = λ⁺(A) + λ⁻(B)
Λ°(CB) = λ⁺(C) + λ⁻(B)

where, λ⁺ and λ⁻ are the molar conductivities of the cation and anion, respectively, and the migration constants are represented by Greek letters.

Calculation:
Using Kohlrausch law,
λ⁺(A) + λ⁻(B) = 73.5 Scm²mol⁻¹
λ⁺(C) + λ⁻(B) = 110.1 Scm²mol⁻¹

Subtracting the first equation from the second equation,
(λ⁺(C) + λ⁻(B)) - (λ⁺(A) + λ⁻(B)) = 110.1 Scm²mol⁻¹ - 73.5 Scm²mol⁻¹
λ⁺(C) - λ⁺(A) = 36.6 Scm²mol⁻¹

Therefore, the limiting molar conductivity of C can be calculated as:
λ⁺(C) = λ⁺(A) + 36.6 Scm²mol⁻¹
λ⁺(C) = 73.5 Scm²mol⁻¹ + 36.6 Scm²mol⁻¹
λ⁺(C) = 110.1 Scm²mol⁻¹

Hence, the limiting molar conductivity of C is 110.1 Scm²mol⁻¹.
Therefore, the correct option is (B) 38.6 S cm²mol⁻¹.
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Molar conductivity for a compound AB is 145.0 Scm2mol-1and for CB is 1...
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Molar conductivity for a compound AB is 145.0 Scm2mol-1and for CB is 110.1 Scm2mol-1. Limiting molar conductivity for A+is 73.5 Scm2mol-1. What is limiting molar conductivity for C+?a)326.6 S cm2mol-1b)38.6 S cm2mol-1c)181.6 S cm2mol-1d)90.8 S cm2mol-1Correct answer is option 'B'. Can you explain this answer?
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Molar conductivity for a compound AB is 145.0 Scm2mol-1and for CB is 110.1 Scm2mol-1. Limiting molar conductivity for A+is 73.5 Scm2mol-1. What is limiting molar conductivity for C+?a)326.6 S cm2mol-1b)38.6 S cm2mol-1c)181.6 S cm2mol-1d)90.8 S cm2mol-1Correct answer is option 'B'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Molar conductivity for a compound AB is 145.0 Scm2mol-1and for CB is 110.1 Scm2mol-1. Limiting molar conductivity for A+is 73.5 Scm2mol-1. What is limiting molar conductivity for C+?a)326.6 S cm2mol-1b)38.6 S cm2mol-1c)181.6 S cm2mol-1d)90.8 S cm2mol-1Correct answer is option 'B'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Molar conductivity for a compound AB is 145.0 Scm2mol-1and for CB is 110.1 Scm2mol-1. Limiting molar conductivity for A+is 73.5 Scm2mol-1. What is limiting molar conductivity for C+?a)326.6 S cm2mol-1b)38.6 S cm2mol-1c)181.6 S cm2mol-1d)90.8 S cm2mol-1Correct answer is option 'B'. Can you explain this answer?.
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