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A liquid was mixed with ethanol and a drop of concentrated H2SO4 was added. A compound with a fruity smell was formed. The liquid was      [AIEEE 2009]
  • a)
    HCHO
  • b)
    CH3COCH3
  • c)
    CH3COOH 
  • d)
    CH3OH
Correct answer is option 'C'. Can you explain this answer?
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Understanding the Reaction
In this experiment, a liquid is mixed with ethanol and concentrated sulfuric acid (H2SO4) is added. The fruity smell indicates the formation of an ester.
Identifying the Liquid
The options provided are:
- a) HCHO (Formaldehyde)
- b) CH3COCH3 (Acetone)
- c) CH3COOH (Acetic acid)
- d) CH3OH (Methanol)
Among these, the only suitable candidate that can react with ethanol to form an ester is CH3COOH (Acetic acid).
Reaction Mechanism
- When acetic acid reacts with ethanol in the presence of concentrated H2SO4, it undergoes a condensation reaction.
- This reaction results in the formation of ethyl acetate, an ester that is known for its fruity smell.
Why Other Options Are Incorrect
- HCHO (Formaldehyde): Does not form a fruity smelling compound when reacted with ethanol. Instead, it leads to different products.
- CH3COCH3 (Acetone): While it can react with alcohols, it does not produce a fruity smell.
- CH3OH (Methanol): Would not produce fruity smelling esters with ethanol and is less likely to participate in this specific reaction.
Conclusion
The fruity smell resulting from the reaction of acetic acid with ethanol and H2SO4 confirms that the liquid must be CH3COOH (Acetic acid). This is the reason why option 'C' is the correct answer.
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A liquid was mixed with ethanol and a drop of concentrated H2SO4 was added. A compound with a fruity smell was formed. The liquid was [AIEEE 2009]a)HCHOb)CH3COCH3c)CH3COOHd)CH3OHCorrect answer is option 'C'. Can you explain this answer?
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