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In a homogenous catalytic reaction, 1.0 M of a substrate band 1.0 μM of a catalyst yields 1.0 mM of a product in 10 s. The turnover frequency (TOF) of the reaction (s-1) is.
  • a)
    10-2
  • b)
    102
  • c)
    10-3
  • d)
    103
Correct answer is option 'B'. Can you explain this answer?
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Homogeneous Catalytic Reaction

- In a homogeneous catalytic reaction, the reactants and the catalyst are present in the same phase (i.e., either liquid or gas).
- The catalyst increases the rate of the reaction by providing an alternate pathway with lower activation energy.

Turnover Frequency (TOF)

- The turnover frequency (TOF) of a catalyst is defined as the number of moles of product formed per mole of catalyst per unit time.
- It is expressed in units of s-1 (i.e., per second).

Calculation of TOF

- Given that 1.0 M of substrate and 1.0 M of catalyst yield 1.0 mM of product in 10 s.
- We need to calculate the turnover frequency (TOF) of the reaction (s-1).

- Number of moles of substrate = 1.0 M x 1.0 L = 1.0 mol
- Number of moles of catalyst = 1.0 M x 1.0 L = 1.0 mol
- Number of moles of product = 1.0 mM x 1.0 L = 0.001 mol
- Time taken for the reaction = 10 s

- TOF = (Number of moles of product formed / Number of moles of catalyst) / Time taken for the reaction

- TOF = (0.001 mol / 1.0 mol) / 10 s
- TOF = 10-4 s-1

- The answer is expressed in s-1, which is equivalent to Hz (Hertz).
- Therefore, the answer is option 'B' (102 Hz).
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In a homogenous catalytic reaction, 1.0 M of a substrate band 1.0 μM of a catalyst yields 1.0 mM of a product in 10 s. The turnover frequency (TOF) of the reaction (s-1) is.a)10-2b)102c)10-3d)103Correct answer is option 'B'. Can you explain this answer?
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