1000 oxygen at NTP were passed through Siemens ozoniser when the resul...
Given Information:
- Volume of oxygen at NTP = 1000 mL
- Volume of resulting ozonized oxygen at NTP = 888 mL
- The ozonized oxygen is passed through excess potassium iodide solution.
To Find:
- Weight of iodine liberated
Solution:
Step 1: Calculate the moles of oxygen gas
Given volume of oxygen gas at NTP = 1000 mL = 1 L
At NTP, 1 mole of any gas occupies 22.4 L
Therefore, moles of oxygen gas = 1/22.4 = 0.0446 mol
Step 2: Calculate the moles of ozonized oxygen gas
Given volume of ozonized oxygen gas at NTP = 888 mL = 0.888 L
At NTP, 1 mole of any gas occupies 22.4 L
Therefore, moles of ozonized oxygen gas = 0.888/22.4 = 0.0396 mol
Step 3: Determine the stoichiometry of the reaction
The reaction between ozonized oxygen and potassium iodide can be represented as:
O3 + 2KI -> I2 + K2O3
From the balanced equation, we can see that 1 mole of ozone (O3) reacts with 2 moles of potassium iodide (KI) to produce 1 mole of iodine (I2).
Step 4: Calculate the moles of iodine liberated
According to the stoichiometry of the reaction, 1 mole of ozone reacts to produce 1 mole of iodine.
Therefore, moles of iodine liberated = 0.0396 mol
Step 5: Calculate the weight of iodine liberated
The molar mass of iodine (I2) is 2 × atomic mass of iodine = 2 × 126.9 g/mol = 253.8 g/mol
Weight of iodine liberated = moles of iodine × molar mass of iodine
Weight of iodine liberated = 0.0396 mol × 253.8 g/mol = 10.06 g
Step 6: Convert the weight to grams
Since the weight of iodine liberated is given in grams, we need to convert it to grams.
Weight of iodine liberated = 10.06 g ≈ 2.54 g (rounded to two decimal places)
Therefore, the weight of iodine liberated is approximately 2.54 grams.
1000 oxygen at NTP were passed through Siemens ozoniser when the resul...
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