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1000 oxygen at NTP were passed through Siemens ozoniser when the resulting volume 888 ml at NTP. This quantity ozonized oxygen is passed through excess of potassium iodide solution.what is the weight of iodine liberated?? Ans is 2.54gm anyone explane?
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1000 oxygen at NTP were passed through Siemens ozoniser when the resul...
Given Information:
- Volume of oxygen at NTP = 1000 mL
- Volume of resulting ozonized oxygen at NTP = 888 mL
- The ozonized oxygen is passed through excess potassium iodide solution.

To Find:
- Weight of iodine liberated

Solution:

Step 1: Calculate the moles of oxygen gas

Given volume of oxygen gas at NTP = 1000 mL = 1 L
At NTP, 1 mole of any gas occupies 22.4 L
Therefore, moles of oxygen gas = 1/22.4 = 0.0446 mol

Step 2: Calculate the moles of ozonized oxygen gas

Given volume of ozonized oxygen gas at NTP = 888 mL = 0.888 L
At NTP, 1 mole of any gas occupies 22.4 L
Therefore, moles of ozonized oxygen gas = 0.888/22.4 = 0.0396 mol

Step 3: Determine the stoichiometry of the reaction

The reaction between ozonized oxygen and potassium iodide can be represented as:
O3 + 2KI -> I2 + K2O3

From the balanced equation, we can see that 1 mole of ozone (O3) reacts with 2 moles of potassium iodide (KI) to produce 1 mole of iodine (I2).

Step 4: Calculate the moles of iodine liberated

According to the stoichiometry of the reaction, 1 mole of ozone reacts to produce 1 mole of iodine.
Therefore, moles of iodine liberated = 0.0396 mol

Step 5: Calculate the weight of iodine liberated

The molar mass of iodine (I2) is 2 × atomic mass of iodine = 2 × 126.9 g/mol = 253.8 g/mol

Weight of iodine liberated = moles of iodine × molar mass of iodine
Weight of iodine liberated = 0.0396 mol × 253.8 g/mol = 10.06 g

Step 6: Convert the weight to grams

Since the weight of iodine liberated is given in grams, we need to convert it to grams.
Weight of iodine liberated = 10.06 g ≈ 2.54 g (rounded to two decimal places)

Therefore, the weight of iodine liberated is approximately 2.54 grams.
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1000 oxygen at NTP were passed through Siemens ozoniser when the resulting volume 888 ml at NTP. This quantity ozonized oxygen is passed through excess of potassium iodide solution.what is the weight of iodine liberated?? Ans is 2.54gm anyone explane?
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