The volume (in mL) of 0.1 M AgNO3required for complex precipitation of...
The chemical reaction between them is...[Cr(H2O)5Cl]Cl2 + {2}AgNO3 ——> {2}AgCl(↓) + [Cr(H2O)5Cl]^2+ + {2}NO3-moles of coordinate compound given = molarity x volume(in litre)mole = 0.01 x (30/1000) = (3/10000)for one mole coordinate compound.. we need 2 mole AgNO3....i.e.,1mole complex ===> 2 mole AgNO3(3/10000) mole ==> (2x3/10000) mole AgNO3molarity = moles/volume (in litre)volume(in litre) = mole / molarityV= (6/10000)/0.1 = (0.6) Litrehence volume required = 0.6litre = 6ml
View all questions of this test
The volume (in mL) of 0.1 M AgNO3required for complex precipitation of...
Understanding the Problem
To determine the volume of 0.1 M AgNO3 required for complex precipitation of chloride ions from the given solution, we need to analyze the components involved.
Components of the Solution
- [Cr(H2O)5Cl]Cl2: This complex contains two chloride ions (Cl-) for each formula unit.
- Volume of the solution: 30 mL (which is 0.030 L).
- Concentration of the complex: 0.01 M.
Calculating moles of Chloride Ions
- Moles of [Cr(H2O)5Cl]Cl2 in 30 mL:
- Moles = Concentration × Volume
- Moles = 0.01 M × 0.030 L = 0.0003 moles.
- Since there are 2 chloride ions per complex, total moles of Cl-:
- Total moles = 0.0003 moles × 2 = 0.0006 moles of Cl-.
Determining Volume of AgNO3 Required
- The reaction for precipitation is:
- AgNO3 + Cl- → AgCl (s).
- This means that 1 mole of AgNO3 is required for 1 mole of Cl-. Hence, we need 0.0006 moles of AgNO3.
- Volume of 0.1 M AgNO3 needed:
- Volume = Moles / Concentration
- Volume = 0.0006 moles / 0.1 M = 0.006 L = 6 mL.
Conclusion
The volume of 0.1 M AgNO3 required for the complete precipitation of the chloride ions in the given solution is approximately 6 mL. Therefore, the correct answer is option 'D'.
The volume (in mL) of 0.1 M AgNO3required for complex precipitation of...
N1V1=N2V2. 0.1*V1 2*0.01*30. V1 = 6