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The IUPAC name for the complex
[ Co(NO2) (NH3)5] Cl2 is :
  • a)
    pentaamminenitrito-N-cobalt(II) Chloride
  • b)
    pentaamminenitrito-N-cobalt(III) Chloride
  • c)
    nitrito-N-pentaamminecobalt(III)chloride
  • d)
    nitrito-N-pentaamminecobalt(II)chloride
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
The IUPAC name for the complex[ Co(NO2)(NH3)5] Cl2is :a)pentaamminenit...
The IUPAC name of the given coordination complex according to the nomenclature rules is Pentamminenitrito-N-cobalt(III)chloride. Hence the correct option is B.
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Most Upvoted Answer
The IUPAC name for the complex[ Co(NO2)(NH3)5] Cl2is :a)pentaamminenit...
B... the Oxidation state of Co is 3 as ammonia is neutral ligand... and then name the ligands alphabetically...
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Community Answer
The IUPAC name for the complex[ Co(NO2)(NH3)5] Cl2is :a)pentaamminenit...
Understanding the Complex
The complex in question is [Co(NO2)(NH3)5]Cl2. To determine the correct IUPAC name, we need to analyze its components and oxidation state.
Components of the Complex
- Cobalt (Co): This is the central metal ion.
- Nitrito (NO2): This ligand is a bidentate ligand that can bind through nitrogen or oxygen. In this case, it's bound through nitrogen (hence the 'N' in the name).
- Ammonia (NH3): This is a neutral ligand, and there are five of them in the complex.
- Chloride (Cl2): This is the counter ion, indicating that the complex is a salt.
Oxidation State of Cobalt
To find the oxidation state of cobalt, we can set up the equation:
- Let x be the oxidation state of Co.
- The nitrito ligand contributes -1.
- Each ammonia ligand contributes 0.
- The total charge of the complex must balance with the counter ions (Cl2 contributes -2).
Thus, we have:
x - 1 + 0 = 0 (since the complex is neutral)
This simplifies to:
x - 1 = 0 → x = +1
However, since the complex has two Cl- ions, the oxidation state of cobalt is actually +3.
Correct IUPAC Name
Given that cobalt is in the +3 oxidation state and the nitrito ligand is attached through nitrogen, the correct IUPAC name is:
pentaamminenitrito-N-cobalt(III) chloride (option B).
Conclusion
- The use of "penta" indicates five ammonia ligands.
- "Nitrito-N" indicates the binding through nitrogen.
- "Cobalt(III)" reflects the +3 oxidation state.
- "Chloride" denotes the presence of Cl- as a counter ion.
Hence, the correct answer is option B, as it accurately represents the structure and oxidation state of the complex.
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The IUPAC name for the complex[ Co(NO2)(NH3)5] Cl2is :a)pentaamminenitrito-N-cobalt(II) Chlorideb)pentaamminenitrito-N-cobalt(III) Chloridec)nitrito-N-pentaamminecobalt(III)chlorided)nitrito-N-pentaamminecobalt(II)chlorideCorrect answer is option 'B'. Can you explain this answer?
Question Description
The IUPAC name for the complex[ Co(NO2)(NH3)5] Cl2is :a)pentaamminenitrito-N-cobalt(II) Chlorideb)pentaamminenitrito-N-cobalt(III) Chloridec)nitrito-N-pentaamminecobalt(III)chlorided)nitrito-N-pentaamminecobalt(II)chlorideCorrect answer is option 'B'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about The IUPAC name for the complex[ Co(NO2)(NH3)5] Cl2is :a)pentaamminenitrito-N-cobalt(II) Chlorideb)pentaamminenitrito-N-cobalt(III) Chloridec)nitrito-N-pentaamminecobalt(III)chlorided)nitrito-N-pentaamminecobalt(II)chlorideCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for The IUPAC name for the complex[ Co(NO2)(NH3)5] Cl2is :a)pentaamminenitrito-N-cobalt(II) Chlorideb)pentaamminenitrito-N-cobalt(III) Chloridec)nitrito-N-pentaamminecobalt(III)chlorided)nitrito-N-pentaamminecobalt(II)chlorideCorrect answer is option 'B'. Can you explain this answer?.
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