Equivalent mass of K2Cr2O7when it acts as an oxidizing agent in acidic...
Equivalent mass of K2Cr2O7when it acts as an oxidizing agent in acidic...
The equivalent mass of K2Cr2O7 when it acts as an oxidizing agent in acidic medium is 49.
Explanation:
Equivalent mass is the molecular weight of a substance divided by its valency.
K2Cr2O7, in acidic medium, acts as an oxidizing agent and gets reduced to Cr3+ ion.
The balanced chemical equation for the reaction is:
K2Cr2O7 + 8H+ + 6e- → 2Cr3+ + 2K+ + 7H2O
From the equation, it can be seen that 1 mole of K2Cr2O7 accepts 6 moles of electrons.
The molecular weight of K2Cr2O7 is 294 g/mol and its valency is 6.
Therefore, the equivalent mass of K2Cr2O7 can be calculated as:
Equivalent mass = Molecular weight/Valency
Equivalent mass = 294/6
Equivalent mass = 49
Hence, the equivalent mass of K2Cr2O7 when it acts as an oxidizing agent in acidic medium is 49.