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Equivalent mass of K2Cr2O7 when it acts as an oxidizing agent in acidic medium?
  • a)
    49
  • b)
    96
  • c)
    194
  • d)
    294
Correct answer is option 'A'. Can you explain this answer?
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Equivalent mass of K2Cr2O7when it acts as an oxidizing agent in acidic...
The equivalent mass of K2Cr2O7 when it acts as an oxidizing agent in acidic medium is 49.

Explanation:

Equivalent mass is the molecular weight of a substance divided by its valency.

K2Cr2O7, in acidic medium, acts as an oxidizing agent and gets reduced to Cr3+ ion.

The balanced chemical equation for the reaction is:
K2Cr2O7 + 8H+ + 6e- → 2Cr3+ + 2K+ + 7H2O

From the equation, it can be seen that 1 mole of K2Cr2O7 accepts 6 moles of electrons.

The molecular weight of K2Cr2O7 is 294 g/mol and its valency is 6.

Therefore, the equivalent mass of K2Cr2O7 can be calculated as:
Equivalent mass = Molecular weight/Valency
Equivalent mass = 294/6
Equivalent mass = 49

Hence, the equivalent mass of K2Cr2O7 when it acts as an oxidizing agent in acidic medium is 49.
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