Which is not true for a standard hydrogen electrode? a)The hydrogen io...
The hydrogen electrode is used as standard with zero reduction potential.(at 1atm, 1M and at room temperature). It is the only metallic electrode which can't consist a solid metal in equilibrium in its ion.
Which is not true for a standard hydrogen electrode? a)The hydrogen io...
The standard hydrogen electrode (SHE) is a reference electrode used in electrochemical measurements to determine the standard electrode potential of other electrodes. It consists of a platinum electrode immersed in a solution of 1 M hydrogen ions (H+) at a temperature of 25°C and a pressure of 1 atmosphere. The correct answer to the question is option 'D', which states that the standard hydrogen electrode does not contain a metallic conductor that absorbs hydrogen.
Explanation:
1. Hydrogen ion concentration is 1 M: The standard hydrogen electrode is immersed in a solution of 1 M hydrogen ions. This concentration is maintained to provide a consistent reference potential for electrochemical measurements. The concentration of H+ ions is not influenced by the presence or absence of a metallic conductor.
2. Temperature is 25°C: The standard temperature for electrochemical measurements is 25°C. This is the temperature at which the standard electrode potentials are determined. The temperature affects the electrode potential, and deviations from 25°C may lead to erroneous measurements. Again, the temperature is not dependent on the presence or absence of a metallic conductor.
3. Pressure of hydrogen is 1 atmosphere: The pressure of hydrogen gas is maintained at 1 atmosphere in the standard hydrogen electrode. This is necessary to ensure consistency in the electrode potential measurements. Pressure is related to the activity of the hydrogen gas, which affects the electrode potential. However, the pressure is not influenced by the presence or absence of a metallic conductor.
4. It does not contain a metallic conductor that absorbs hydrogen: This statement is true and is the correct answer to the question. The standard hydrogen electrode does not contain a metallic conductor that absorbs hydrogen. It consists of a platinum electrode that is not reactive or absorbent towards hydrogen gas. The platinum electrode acts as an inert conductor, allowing the transfer of electrons between the electrode and the solution. The absence of a metallic conductor that absorbs hydrogen ensures that the electrode potential is solely determined by the H+/H2 half-cell reaction and is not influenced by any other reactions occurring at the electrode surface.
In conclusion, the correct answer is option 'D' because the standard hydrogen electrode does not contain a metallic conductor that absorbs hydrogen. The other statements (options 'A', 'B', and 'C') are true for a standard hydrogen electrode.