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To an evacuated vessel with movable piston under external pressure of 1 atm, 0.1 mole of Fie and 0.1 mole of an unknown compound (vapour pressure 0.68 atm at 0°C) are introduced. Considering the ideal gas behaviour, the total volume (in litre) of the gases 0°C is close to...
[IITJEE 2011]
    Correct answer is '7'. Can you explain this answer?
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    To an evacuated vessel with movable piston under external pressure of ...
    Let nx mole of unknown compound be present in vapour form so its partial pressure can be

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    To an evacuated vessel with movable piston under external pressure of ...
    Let nx mole of unknown compound be present in vapour form so its partial pressure is
    0.68 = (nx/nx+0.1)×1 atm
    nx+0.1/nx = 1/0.68 = 1.47
    0.1/nx = 0.47
    nx = 0.212
    Applying ideal gas equation,
    1×V = (0.212/0.1)×0.0821×273
    V = 7
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    To an evacuated vessel with movable piston under external pressure of 1 atm, 0.1 mole of Fie and 0.1 mole of an unknown compound (vapour pressure 0.68 atm at 0°C) are introduced. Considering the ideal gas behaviour, the total volume (in litre) of the gases 0°C is close to...[IITJEE 2011]Correct answer is '7'. Can you explain this answer?
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