1.12 ml of gas on STP is obtained when action of the methyl magnesium ...
ROH CH3MgI----CH4 ROMgI
A/q,
4.12mg of ROH gives 1.12ml ofCH4
So,for22400ml,
4.12/1.12*22400=82.4gr
1.12 ml of gas on STP is obtained when action of the methyl magnesium ...
Introduction
The reaction between methyl magnesium iodide (a Grignard reagent) and alcohol (ROH) serves as an important example in organic synthesis. This process leads to the formation of an alkane and a magnesium salt.
Understanding Grignard Reagents
- Grignard reagents, like methyl magnesium iodide, are organomagnesium compounds.
- They react with electrophiles, such as carbonyl compounds and alcohols, facilitating the formation of new carbon-carbon bonds.
Reaction with Alcohol
- When methyl magnesium iodide reacts with an alcohol (ROH):
- The alcohol acts as a proton donor.
- The Grignard reagent behaves as a nucleophile, attacking the alcohol, leading to the liberation of a gas.
Gas Formation
- The 1.12 ml of gas produced at Standard Temperature and Pressure (STP) is typically methane (CH4).
- This indicates that a methyl group is transferred from the Grignard reagent, resulting in the formation of methane.
Alcohol Molecule Characteristics
- The general formula for alcohols is R-OH, where R represents a hydrocarbon chain.
- Alcohols are characterized by their hydroxyl (-OH) functional group, which makes them polar and capable of hydrogen bonding.
Conclusion
- The reaction between methyl magnesium iodide and alcohol showcases the versatility of Grignard reagents in organic synthesis.
- Understanding this interaction highlights the importance of alcohols in generating valuable compounds and gases like methane in chemical reactions.