Which pair is not in the correct order of lattice energy?a)KCl < M...
Based on Fajans' rule,
Smaller the size of cation, larger the size of anion, larger the charge,
d-f-Aelectrons present then larger the polarising power, larger the covalent nature and larger the lattice energy.



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Which pair is not in the correct order of lattice energy?a)KCl < M...
Explanation:
Lattice Energy:
Lattice energy is the energy released when gaseous ions form a solid compound. It is a measure of the strength of the ionic bond in a compound.
Correct Order of Lattice Energy:
The correct order of lattice energy is determined by the charges of the ions and the size of the ions. Generally, the higher the charges of the ions and the smaller their size, the higher the lattice energy.
Incorrect Pair:
The pair that is not in the correct order of lattice energy is option D - BeCO3 = MgCO3. This is because the lattice energy of a compound is influenced by the charges of the ions and the sizes of the ions. In this case, the charges of the ions in BeCO3 and MgCO3 are the same (Be2+ and Mg2+), but the size of the ions is different. Beryllium ions (Be2+) are smaller in size compared to magnesium ions (Mg2+), which results in a higher lattice energy for BeCO3 compared to MgCO3. Therefore, the correct order should be BeCO3 > MgCO3.
Correct Order of Lattice Energy:
- KCl > MgO
- AlN > MgO
- BeCO3 > MgCO3
Therefore, the correct order of lattice energy among the given pairs is:
a) KCl > MgO
b) AlN > MgO
c) BeCO3 > MgCO3