Which of the following statements are not correct?a)In canonical struc...
In NaCl the ions are not free in solid state but they are strongly bonded through electrostatic forces, hence is not a good conductor of electricity in solid state
A canonicalstructure is also known as a resonance structure, i.e. one of possibly more than one contributing structures that combine to produce the true, resonance hybrid structure. The arrangement of atoms remains the same.
Correct option is A and C.
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Which of the following statements are not correct?a)In canonical struc...
Incorrect Statements:
a) In canonical structures, there is a difference in the arrangement of atoms.
c) NaCl being an ionic compound is a good conductor of electricity in the solid state.
Explanation:
a) In canonical structures, there is a difference in the arrangement of atoms.
- This statement is incorrect. In canonical structures, also known as resonance structures, there is no difference in the arrangement of atoms. Instead, the only difference lies in the placement of electrons.
- Resonance occurs when multiple equivalent Lewis structures can be drawn for a molecule or ion, differing only in the placement of electrons. The actual structure is considered as a combination or hybrid of all the resonance structures.
- For example, in the case of ozone (O3), the molecule can be represented by two resonance structures where the double bond alternates between the two oxygen atoms. However, the actual structure is a hybrid of these two resonance forms, with the double bond delocalized or spread out over all three oxygen atoms.
- Therefore, the arrangement of atoms remains the same in resonance structures, and the differences lie in the electron distribution.
c) NaCl being an ionic compound is a good conductor of electricity in the solid state.
- This statement is incorrect. Although NaCl is an ionic compound, it is not a good conductor of electricity in the solid state.
- Ionic compounds consist of a lattice of positive and negative ions held together by electrostatic forces. In the solid state, these ions are locked in place and cannot move freely. Therefore, ionic compounds do not conduct electricity in the solid state.
- However, when an ionic compound like NaCl is dissolved in water or melted, the ions become free to move and can conduct electricity. This is because the water molecules or the liquid medium allows the ions to separate and move, creating a pathway for the flow of electric current.
- In the solid state, NaCl and other ionic compounds are insulators rather than conductors.
- Metals, on the other hand, are good conductors of electricity in the solid state because they have delocalized electrons that are free to move throughout the metal lattice.
- Therefore, NaCl is not a good conductor of electricity in the solid state.
Which of the following statements are not correct?a)In canonical struc...
C
because sodium chloride is a good conduter of electricity in molten state
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