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The hybridisation and geometry of BrF3 molecules are :
  • a)
    sp3d and T shaped
  • b)
    sp2d 2 and tetragonal
  • c)
    sp3d and bent
  • d)
    none of these
Correct answer is option 'A'. Can you explain this answer?
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Hybridization of BrF3
The hybridization of bromine trifluoride (BrF3) is determined by its electron geometry and the number of bonding and non-bonding electron pairs present on the central bromine atom.
- BrF3 contains 5 electron pairs around the bromine atom:
- 3 bonding pairs (from the Br-F bonds)
- 2 lone pairs
Geometry of BrF3
The arrangement of these electron pairs leads to a specific molecular geometry.
- The electron pair geometry is trigonal bipyramidal due to the five pairs.
- However, the presence of two lone pairs alters the molecular shape.
Molecular Shape
- The lone pairs occupy equatorial positions in the trigonal bipyramidal arrangement to minimize repulsion.
- This leaves the three fluorine atoms in a T-shaped configuration.
Conclusion
- Therefore, the hybridization of BrF3 is sp3d, and its geometry is T-shaped.
This makes option 'A' the correct choice.
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The hybridisation and geometry of BrF3molecules are :a)sp3d and T shapedb)sp2d 2and tetragonalc)sp3d and bentd)none of theseCorrect answer is option 'A'. Can you explain this answer?
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