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Based on the following thermochemical data of the given process, answer the questions.

 
Q. Bond energy of (C—H) bond is 
  • a)
    82 kcal mol-1
  • b)
    -99 kcal mol-1
  • c)
    99 kcal mol-1
  • d)
    112 kcal mol-1
Correct answer is option 'C'. Can you explain this answer?
Verified Answer
Based on the following thermochemical data of the given process, answe...
For C3H8 : 3C + 4H2 → C3H8 ; ∆H1
For C3H8 : 2C + 3H2 → C2H6 ; ∆H2
∆H1 = -[2(C-C)+8(C-H)]+[3Cs→g+4(H-H)]     -(I)
∆H2 = -[1(C-C)+6(C-H)]+[2Cs→g+3(H-H)]     -(2)
Let bond energy of C-C be x kcal and bond energy of C-H be y  kcal.
From eqn I and 2
 ∆H1 = -[2x+8y]+[3×172+4×104]     -(3)
∆H2 = -[x+6y]+[2×172+3×104]     -(4)
Also given, C+O2 → CO2; ∆H = -94.0 kcal     -(5)
H2 + ½ O2 → H2O ; ∆H = -68.0 kcal      -(6)
C2H6 + 7/2 O2 → 2CO2 + 3H2O ; ∆H = -372 kcal     -(7)
C3H8 + 5O2  → 3CO2 + 4H2O ; ∆H = -530 kcal     -(8)
By inspection method,  2 × (5) + 3 × (6) - (7) gives
2C + 3H2 → C2H6 ; ∆H2 = -20 kcal
And  3×(5) + 4×(6) -(8)
3C + 4H2 → C3H8 ; ∆H3 = -20 kcal 
By eqn. (3), (4), (9) and (10)
x+6y = 676
2x+8y = 956
x = 82 kcal and y = 99 kcal
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Based on the following thermochemical data of the given process, answer the questions.Q.Bond energy of (C—H) bond isa)82 kcal mol-1b)-99 kcal mol-1c)99 kcal mol-1d)112 kcal mol-1Correct answer is option 'C'. Can you explain this answer?
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