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Given, ΔfH° of HCI (g) is - 22 . 10 kcal mol-1 and ΔSolutionH° (heat of solution) of HCI (g) is - 17.9 kcal mol-1. Thus, ΔfH ° of Cl- (aq) is
  • a)
     -40.0 kcal mol-1 
  • b)
    +40.0 kcal mol-1 
  • c)
    +17.9 kcal mol-1
  • d)
    +22.1 kcal mol-1
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
Given, ΔfH° of HCI (g) is - 22 . 10 kcal mol-1 and ΔSol...
½ H2(g) + ½ Cl2(g) → HCl(g) ∆fH° = -22.10 kcal mol-1  -----(I)
HCl(g) + H2O(l) → H+(aq) + Cl-(aq)     ∆solutionH° = -17.9 kcal mol-1 -----(II)
Let us add (I) and (II), we get
½ H2(g) + ½ Cl2(g) → H+(aq) + Cl-(aq) ∆rH° = -40.0 kcal mol-1
rH° = ∑∆Hproduct  -  ∑∆Hreactant = ∆fHCl- (since enthalpy of formation of H, H2 and Cl2 are 0)
fHCl- = -40.0
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Most Upvoted Answer
Given, ΔfH° of HCI (g) is - 22 . 10 kcal mol-1 and ΔSol...
Explanation:

Given Data:
- fH of HCl (g) = -22.10 kcal mol-1
- SolutionH of HCl (g) = -17.9 kcal mol-1

Calculating fH of Cl-(aq):
- The formation of Cl-(aq) from HCl (g) involves the dissociation of HCl into H+ and Cl- ions.
- The enthalpy change for this process is equal to the sum of the enthalpies of formation of the products minus the enthalpy of formation of the reactants.
- The enthalpy of formation of H+ is 0 kcal mol-1 as it is a free ion in solution.
- Therefore, fH of Cl-(aq) = fH of HCl (g) - SolutionH of HCl (g)
- fH of Cl-(aq) = -22.10 kcal mol-1 - (-17.9 kcal mol-1)
- fH of Cl-(aq) = -22.10 kcal mol-1 + 17.9 kcal mol-1
- fH of Cl-(aq) = -4.2 kcal mol-1

Answer:
- fH of Cl-(aq) = -4.2 kcal mol-1
Therefore, the correct answer is option 'A', which states that the fH of Cl-(aq) is -4.2 kcal mol-1.
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Given, ΔfH° of HCI (g) is - 22 . 10 kcal mol-1 and ΔSolutionH° (heat of solution) of HCI (g) is - 17.9 kcal mol-1. Thus, ΔfH ° of Cl-(aq) isa)-40.0 kcal mol-1b)+40.0 kcal mol-1c)+17.9 kcal mol-1d)+22.1 kcal mol-1Correct answer is option 'A'. Can you explain this answer?
Question Description
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