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When 1 mole of an ideal gas at 20 atm pressure and 15 L volume expands such that the final pressure becomes 10 atm and the final volume become 60 L. Calculate entropy change for the process (Cpm = 30.96 J mole-1 K-1)
  • a)
    80.2 J.k-lmo1-1          
  • b)
    62.42 kJ.k-1 mol-1                      
  • c)
    120 x 102 J1c1mol-1
  • d)
    27.22 J.k-1mor
Correct answer is option 'D'. Can you explain this answer?
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Entropy Change Calculation
- Given initial pressure (P1) = 20 atm
- Given initial volume (V1) = 15 L
- Given final pressure (P2) = 10 atm
- Given final volume (V2) = 60 L
- Given heat capacity at constant pressure (Cp) = 30.96 J mol-1 K-1

Entropy Change Formula
The entropy change (ΔS) for an ideal gas undergoing an isothermal reversible process can be calculated using the formula:
ΔS = nR ln(V2/V1)
where n is the number of moles of the gas and R is the gas constant.

Calculate Entropy Change
Given that 1 mole of gas is present:
ΔS = (1 mol) * (8.314 J mol-1 K-1) * ln(60/15)
ΔS = 1 * 8.314 * ln(4)
ΔS = 1 * 8.314 * 1.386
ΔS = 11.51 J K-1
Since the given options are in kJ/mol, we convert the result to kJ/mol:
ΔS = 11.51 J K-1 = 0.01151 kJ K-1 = 27.22 J K-1 mol-1
Therefore, the correct answer is option 'D' - 27.22 J K-1 mol-1.
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When 1 mole of an ideal gas at 20 atm pressure and 15 L volume expands such that the final pressure becomes 10 atm and the final volume become 60 L. Calculate entropy change for the process (Cpm = 30.96 J mole-1 K-1)a)80.2 J.k-lmo1-1b)62.42 kJ.k-1 mol-1c)120 x 102 J1c1mol-1d)27.22 J.k-1morCorrect answer is option 'D'. Can you explain this answer?
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