Acidity ofBF3can be explained on the basis of which of the following c...
Sol: (c) According to Lewis concept, a positively charged or an electron deficient species acts as Lewis acid. BF3 is an electron deficient compound with B having 6 electrons only.
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Acidity ofBF3can be explained on the basis of which of the following c...
Acidity of BF3 can be explained on the basis of Lewis concept.
Explanation:
The Lewis concept of acids and bases was proposed by Gilbert N. Lewis in 1923. According to this concept, an acid is defined as an electron pair acceptor, while a base is defined as an electron pair donor.
Acidity of BF3:
BF3 is a Lewis acid because it can accept an electron pair from a Lewis base. In BF3, the boron atom is electron deficient and has an incomplete octet. It has only six valence electrons, so it can accept a pair of electrons from a Lewis base to complete its octet.
When BF3 reacts with a Lewis base, such as NH3, the boron atom accepts a lone pair of electrons from the nitrogen atom in NH3. This forms a coordinate covalent bond, also known as a dative bond, between the boron and nitrogen atoms. The resulting species is called an adduct.
BF3 + NH3 → BF3NH3
In this reaction, BF3 acts as an acid because it accepts an electron pair from NH3, which acts as a base. The Lewis base (NH3) donates its electron pair to the electron-deficient boron atom in BF3, forming a more stable adduct.
Conclusion:
The acidity of BF3 can be explained on the basis of the Lewis concept because it acts as a Lewis acid by accepting an electron pair from a Lewis base. This concept provides a broader understanding of acidity and allows for the characterization of compounds that cannot be explained by other concepts such as the Arrhenius or Bronsted-Lowry concepts.
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