Which of the following solution will have pH close to 1.0 ?a)100 ml of...
Understanding pH Calculation
To determine which solution has a pH close to 1.0, we need to analyze the concentrations of HCl and NaOH in each option. A pH of 1.0 indicates a highly acidic solution, which corresponds to a high concentration of hydrogen ions (H+).
Acid-Base Neutralization
- HCl (Hydrochloric acid) is a strong acid, fully dissociating in solution.
- NaOH (Sodium hydroxide) is a strong base, also fully dissociating in solution.
When mixed, these two will undergo neutralization. The remaining concentration of H+ ions will determine the final pH.
Option Analysis
1. Option A: 100 ml of M/100 HCl + 100 ml of M/10 NaOH
- M/100 HCl: 0.01 M concentration
- M/10 NaOH: 0.1 M concentration
- NaOH will neutralize HCl, resulting in a less acidic solution.
2. Option B: 55 ml of M/10 HCl + 45 ml of M/10 NaOH
- M/10 HCl: 0.1 M concentration
- M/10 NaOH: 0.1 M concentration
- These will neutralize each other, leading to a pH around 7.
3. Option C: 10 ml of M/10 HCl + 90 ml of M/10 NaOH
- M/10 HCl: 0.1 M concentration
- M/10 NaOH: 0.1 M concentration
- NaOH will significantly neutralize HCl, resulting in a higher pH.
4. Option D: 75 ml of M/5 HCl + 25 ml of M/5 NaOH
- M/5 HCl: 0.2 M concentration
- M/5 NaOH: 0.2 M concentration
- The excess HCl will ensure a highly acidic solution, keeping the pH low.
Conclusion
- Final pH of Option D: Since it contains more HCl than NaOH, the solution remains acidic with a pH close to 1.0. Other options lead to neutralization, resulting in higher pH values. Thus, option D is correct.
Which of the following solution will have pH close to 1.0 ?a)100 ml of...
D is correct.