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The order of solubility of lithium halides in non-polar solvents follows the order :
  • a)
    LiI > LiBr > LiCl > LiF
  • b)
    Li F > LiI > LiBr > LiCl
  • c)
    LiCl > LiF > Lil > LiBr
  • d)
    LiBr > LiCl > LiF > LiI
Correct answer is option 'A'. Can you explain this answer?
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The order of solubility of lithium halides in non-polar solvents follo...
Fajan rule solubility inpolar solvent ∞ Ionic character solubility in non polar ∞ cavalent character solvent
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The order of solubility of lithium halides in non-polar solvents follo...
Order of Solubility of Lithium Halides in Non-polar Solvents

The solubility of lithium halides in non-polar solvents is determined by the ionic character of the compound. The order of solubility can be predicted by the size of the halide ion and the lattice energy of the compound. The smaller the halide ion, the more soluble the compound will be in non-polar solvents.

Order of Solubility:

a) LiI > LiBr > LiCl > LiF

Explanation:

1. LiI is the most soluble because it has the largest halide ion among the lithium halides. It forms a weaker ionic bond with lithium, which makes it more soluble in non-polar solvents.

2. LiBr is less soluble than LiI because it has a smaller halide ion. The smaller size of the bromide ion results in a stronger ionic bond with lithium, which reduces its solubility in non-polar solvents.

3. LiCl is less soluble than LiBr because it has an even smaller halide ion. The smaller size of the chloride ion results in an even stronger ionic bond with lithium, which further reduces its solubility in non-polar solvents.

4. LiF is the least soluble among the lithium halides because it has the smallest halide ion. The small size of the fluoride ion results in a very strong ionic bond with lithium, which makes it almost insoluble in non-polar solvents.

Conclusion:

In summary, the order of solubility of lithium halides in non-polar solvents follows the trend LiI > LiBr > LiCl > LiF. This trend is based on the size of the halide ion and the strength of the ionic bond between lithium and the halide ion.
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