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Match the systems in Column I with their corresponding characterstics from Column II
Codes 
    
  • a)
    a
  • b)
    b
  • c)
    c
  • d)
    d
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
Match the systems in Column I with their corresponding characterstics ...
The correct answer is option A
Butanone has three tautomers other than the mentioned compound itself and acts as a H-bond acceptor
3-pentanone has two tautomers other than the mentioned compound itself and acts as a H-bond acceptor
Methanamide has two tautomers other than the mentioned compound itself, forms intermolecular H-bonds with its own molecules and acts as a H-bond acceptor 
Ethane nitrile  has two tautomers other than the mentioned compound itself and acts as a H-bond acceptor
1. Butanone has three tautomers other than the mentioned compound itself and acts as an H-bond acceptor.
• Butanone (CH3- CO - CH2CH3) can exist in different tautomeric forms. The keto form is the most stable, but it can also undergo keto-enol tautomerism. However, saying it has three tautomers may be misleading. It primarily exists as the keto form with a minor contribution from the enol form. Also, ketones like butanone can act as H-bond acceptors due to the oxygen atom in the carbonyl group. So the statement is correct.
2. 3-pentanone has two tautomers other than the mentioned compound itself and acts as an H-bond acceptor.
• 3-pentanone (CH3- CO - CH2CH2- CH3) can undergo keto-enol tautomerism, so it has an enol form as a tautomer. Also, ketones can act as H-bond acceptors. So the statement is correct.
3. Methanamide has two tautomers other than the mentioned compound itself, forms intermolecular H-bonds with its own molecules, and acts as an H-bond acceptor.
• Methanamide (HCONH2) can exist in different tautomeric forms due to the possibility of hydrogen migration. It can form intermolecular H-bonds with its own molecules, and as an amide, it acts as an H-bond acceptor. So the statement is correct.
4. Ethane nitrile has two tautomers other than the mentioned compound itself and acts as an H-bond acceptor.
• Ethane nitrile (CH3CH2- CN) can undergo tautomerism involving the movement of a hydrogen atom. Also, nitriles like ethane nitrile can act as H-bond acceptors due to the electronegative nitrogen atom. So the statement is correct
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Most Upvoted Answer
Match the systems in Column I with their corresponding characterstics ...
The correct answer is option A
i. Butanone- q) Has three tautomers other than the mentioned compound.
s) Acts as H-bonds acceptor.
ii. 3-pentanone- p) has two tautomer’s other than the mentioned compound itself
s) Acts as H-bonds acceptor.
iii. Methanamide - p) has two tautomer’s other than the mentioned compound itself
r) Form intermolecular H-bonds with its own molecules.
s) Acts as H-bonds acceptor.
Iv. Ethane nitrite - p) has two tautomer’s other than the mentioned compound itself
s) Acts as H-bonds acceptor.
 
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Match the systems in Column I with their corresponding characterstics ...
1-p
2-q
3-r
4-s
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