Which among the following statement is not true for rate constant of a...
Rate constant is independent of concentration of reactant.
View all questions of this test
Which among the following statement is not true for rate constant of a...
Rate Constant of a Reaction
Rate constant is an important parameter in chemical kinetics that determines the rate of a chemical reaction. It is denoted by k and has different units depending upon the order of the reaction. The rate constant has the following characteristics:
Definite value at a particular temperature
The rate constant is a specific value that is determined experimentally at a particular temperature. It is a constant value that remains the same for a given reaction at a given temperature. However, it can change with a change in temperature.
Changes with temperature
The rate constant is dependent upon temperature. It increases with an increase in temperature and decreases with a decrease in temperature. This is because the rate of reaction depends on the energy of the reacting molecules, which increases with an increase in temperature.
Unit of rate constant depend upon the order of reaction
The unit of rate constant depends upon the order of the reaction. For a first-order reaction, the unit of k is s-1, for a second-order reaction, it is dm3 mol-1 s-1, and for a zero-order reaction, it is mol dm-3 s-1.
Rate constant depend upon the concentration of the reactants
This statement is not true. The rate constant is independent of the concentration of the reactants. It is only dependent upon temperature and the nature of the reaction. The rate of reaction depends on the concentration of the reactants, but the rate constant remains the same for a given reaction at a given temperature.
Conclusion
In conclusion, the rate constant is a constant value that has a definite value at a particular temperature and changes with temperature. Its unit depends upon the order of the reaction but is independent of the concentration of the reactants.
Which among the following statement is not true for rate constant of a...
The rate constant is only affected by the type of a reaction(order of a reaction) and temperature.
for instance when a given reaction is reversed the K2 = 1/K1.
if the temperature is Increased the rate constant also increases.