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Statement-1 : An important feature of Fluorite structures is that cations being large in size occupy FCC lattice points whereas anions occupy all the tetrahedral voids giving the formula unit AB2 (A : cation, B : anion).
Statement-2 : There are 6 cations and 12 anions per FCC unit cell of the Fluorite structure.
  • a)
    Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.           
  • b)
    Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.           
  • c)
    Statement-1 is True, Statement-2 is False.           
  • d)
    Statement-1 is False, Statement-2 is True
Correct answer is option 'C'. Can you explain this answer?
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Statement-1 :An important feature of Fluorite structures is that catio...
Based on Fluorite structure of CaF2
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Statement-1 :An important feature of Fluorite structures is that catio...
Statement-1: An important feature of Fluorite structures is that cations being large in size occupy FCC lattice points whereas anions occupy all the tetrahedral voids giving the formula unit AB2 (A: cation, B: anion).
Statement-2: There are 6 cations and 12 anions per FCC unit cell of the Fluorite structure.

Explanation:

Fluorite Structure:
The fluorite structure is a type of crystal structure commonly found in compounds like calcium fluoride (CaF2) and other similar compounds. It is a cubic close-packed (CCP) structure with anions occupying all the tetrahedral voids and cations occupying the face-centered cubic (FCC) lattice points.

Statement-1:
An important feature of Fluorite structures is that cations, which are larger in size, occupy the FCC lattice points. This means that the cations are located at the corners and centers of each face of the unit cell. On the other hand, anions occupy all the tetrahedral voids, which are the spaces between the cations. The formula unit for the fluorite structure is AB2, where A represents the cation and B represents the anion.

Statement-2:
In an FCC unit cell of the fluorite structure, there are 6 cations and 12 anions. This can be determined by analyzing the arrangement of cations and anions in the unit cell. Since the FCC unit cell has 8 corners and each corner is shared by 8 unit cells, there are a total of 8 x 1/8 = 1 cation per unit cell. Additionally, since the FCC unit cell has 6 faces and each face is shared by 2 unit cells, there are a total of 6 x 1/2 = 3 cations per unit cell. Therefore, the total number of cations in an FCC unit cell of the fluorite structure is 1 + 3 = 4.

Similarly, for anions, each tetrahedral void is shared by 4 unit cells. Since there are 4 tetrahedral voids in an FCC unit cell, there are a total of 4 x 1/4 = 1 anion per unit cell. Additionally, each face of the unit cell is shared by 2 tetrahedral voids. Since there are 6 faces in an FCC unit cell, there are a total of 6 x 1/2 = 3 anions per unit cell. Therefore, the total number of anions in an FCC unit cell of the fluorite structure is 1 + 3 = 4.

From the above analysis, it is clear that there are 4 cations and 4 anions in an FCC unit cell of the fluorite structure, which contradicts Statement-2. Hence, Statement-2 is false.

Conclusion:
Based on the explanations above, Statement-1 is true, but Statement-2 is false. Therefore, the correct answer is option 'c' - Statement-1 is true, Statement-2 is false.
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Statement-1 :An important feature of Fluorite structures is that cations being large in size occupy FCC lattice points whereas anions occupy all the tetrahedral voids giving the formula unit AB2(A : cation, B : anion).Statement-2 :There are 6 cations and 12 anions per FCC unit cell of the Fluorite structure.a)Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.b)Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.c)Statement-1 is True, Statement-2 is False.d)Statement-1 is False, Statement-2 is TrueCorrect answer is option 'C'. Can you explain this answer?
Question Description
Statement-1 :An important feature of Fluorite structures is that cations being large in size occupy FCC lattice points whereas anions occupy all the tetrahedral voids giving the formula unit AB2(A : cation, B : anion).Statement-2 :There are 6 cations and 12 anions per FCC unit cell of the Fluorite structure.a)Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.b)Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.c)Statement-1 is True, Statement-2 is False.d)Statement-1 is False, Statement-2 is TrueCorrect answer is option 'C'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Statement-1 :An important feature of Fluorite structures is that cations being large in size occupy FCC lattice points whereas anions occupy all the tetrahedral voids giving the formula unit AB2(A : cation, B : anion).Statement-2 :There are 6 cations and 12 anions per FCC unit cell of the Fluorite structure.a)Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.b)Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.c)Statement-1 is True, Statement-2 is False.d)Statement-1 is False, Statement-2 is TrueCorrect answer is option 'C'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Statement-1 :An important feature of Fluorite structures is that cations being large in size occupy FCC lattice points whereas anions occupy all the tetrahedral voids giving the formula unit AB2(A : cation, B : anion).Statement-2 :There are 6 cations and 12 anions per FCC unit cell of the Fluorite structure.a)Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.b)Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.c)Statement-1 is True, Statement-2 is False.d)Statement-1 is False, Statement-2 is TrueCorrect answer is option 'C'. Can you explain this answer?.
Solutions for Statement-1 :An important feature of Fluorite structures is that cations being large in size occupy FCC lattice points whereas anions occupy all the tetrahedral voids giving the formula unit AB2(A : cation, B : anion).Statement-2 :There are 6 cations and 12 anions per FCC unit cell of the Fluorite structure.a)Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.b)Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.c)Statement-1 is True, Statement-2 is False.d)Statement-1 is False, Statement-2 is TrueCorrect answer is option 'C'. Can you explain this answer? in English & in Hindi are available as part of our courses for Class 12. Download more important topics, notes, lectures and mock test series for Class 12 Exam by signing up for free.
Here you can find the meaning of Statement-1 :An important feature of Fluorite structures is that cations being large in size occupy FCC lattice points whereas anions occupy all the tetrahedral voids giving the formula unit AB2(A : cation, B : anion).Statement-2 :There are 6 cations and 12 anions per FCC unit cell of the Fluorite structure.a)Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.b)Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.c)Statement-1 is True, Statement-2 is False.d)Statement-1 is False, Statement-2 is TrueCorrect answer is option 'C'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of Statement-1 :An important feature of Fluorite structures is that cations being large in size occupy FCC lattice points whereas anions occupy all the tetrahedral voids giving the formula unit AB2(A : cation, B : anion).Statement-2 :There are 6 cations and 12 anions per FCC unit cell of the Fluorite structure.a)Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.b)Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.c)Statement-1 is True, Statement-2 is False.d)Statement-1 is False, Statement-2 is TrueCorrect answer is option 'C'. Can you explain this answer?, a detailed solution for Statement-1 :An important feature of Fluorite structures is that cations being large in size occupy FCC lattice points whereas anions occupy all the tetrahedral voids giving the formula unit AB2(A : cation, B : anion).Statement-2 :There are 6 cations and 12 anions per FCC unit cell of the Fluorite structure.a)Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.b)Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.c)Statement-1 is True, Statement-2 is False.d)Statement-1 is False, Statement-2 is TrueCorrect answer is option 'C'. Can you explain this answer? has been provided alongside types of Statement-1 :An important feature of Fluorite structures is that cations being large in size occupy FCC lattice points whereas anions occupy all the tetrahedral voids giving the formula unit AB2(A : cation, B : anion).Statement-2 :There are 6 cations and 12 anions per FCC unit cell of the Fluorite structure.a)Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.b)Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.c)Statement-1 is True, Statement-2 is False.d)Statement-1 is False, Statement-2 is TrueCorrect answer is option 'C'. Can you explain this answer? theory, EduRev gives you an ample number of questions to practice Statement-1 :An important feature of Fluorite structures is that cations being large in size occupy FCC lattice points whereas anions occupy all the tetrahedral voids giving the formula unit AB2(A : cation, B : anion).Statement-2 :There are 6 cations and 12 anions per FCC unit cell of the Fluorite structure.a)Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.b)Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.c)Statement-1 is True, Statement-2 is False.d)Statement-1 is False, Statement-2 is TrueCorrect answer is option 'C'. Can you explain this answer? tests, examples and also practice Class 12 tests.
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