1 propene treated with hot alkaline KMnO4 what is the product obtained...
When propene is treated with hot alkaline Potassium permangante (KMnO4), it forms Ethanoic acid (CH3COOH) and Formic acid or simply the Methanoic acid (HCOOH)is formed in the product side.
CH2=CH−CH3 ==>CH3COOH + HCOOH.
As you can see the above equation CH2=CH–CH3 (C3H6) Propane is treated with Hot alkaline Potassium permanganate (KMnO4) to form Ethanoic acid and Formic acid.
The formic acid decomposes to water and carbon dioxide.
HCOOH→H2O+CO2
This is oxidative cleavage reaction.
1 propene treated with hot alkaline KMnO4 what is the product obtained...
Product obtained:
The product obtained when propene is treated with hot alkaline KMnO4 is propan-1,2-diol or 1,2-propylene glycol.
Explanation:
The reaction between propene and hot alkaline KMnO4 involves the addition of two hydroxyl groups to the double bond in propene. The reaction proceeds through the following steps:
1. Addition of hydroxyl groups: In the first step, the double bond in propene attacks the MnO4- ion, resulting in the formation of a cyclic intermediate. This intermediate then reacts with water to form two hydroxyl groups attached to the carbon atoms of the double bond.
2. Oxidation: The two hydroxyl groups are then oxidized by the MnO4- ion to form two aldehyde groups.
3. Acid-catalysed hydration: The aldehyde groups are then hydrated to form 1,2-propylene glycol in the presence of acid catalyst.
Overall reaction:
Propene + KMnO4 + OH- → 1,2-propylene glycol + MnO2 + K+ + H2O
Significance:
Propan-1,2-diol or 1,2-propylene glycol is an important chemical used in the production of various products such as antifreeze, solvents, and cosmetics. The reaction between propene and hot alkaline KMnO4 is a useful method for the production of this compound.
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