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Which are π-bonded organometallic compounds?
- a)[Cr(η6 — (C6H6)]
- b)[Fe(CO)5]
- c)K[PtCI3η2 - C2H4]
- d)[Fe(η5 - C5H5)2]
Correct answer is option 'A,C,D'. Can you explain this answer?
Verified Answer
Which are π-bonded organometallic compounds?a)[Cr(η6 —...
η6 -arene is 6-electron ligand, η2 — C2H4 is 2-electron ligand η6-cyclopentadienyl is 5-electron donor. All these 3 ligands creates π-bonded complex. CO as a ligand is sigma donor and pi-acceptor ligand.
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Which are π-bonded organometallic compounds?a)[Cr(η6 —...
Explanation:
Bonded organometallic compounds:
- [Cr(6 (C6H6)]: This compound contains a benzene ligand bonded to a chromium atom. The bond between the benzene ligand and the chromium atom is a π-bond.
- K[PtCl3(C2H4)]: In this compound, the ethylene ligand is bonded to the platinum atom through a π-bond. The presence of the π-bond indicates that this is an organometallic compound.
- [Fe(η5-C5H5)2]: This compound contains two cyclopentadienyl ligands bonded to an iron atom. The bonds between the cyclopentadienyl ligands and the iron atom are π-bonds.
Therefore, the correct options that represent π-bonded organometallic compounds are A, C, and D. These compounds exhibit π-bonding between the metal atom and the organic ligands, making them organometallic in nature.
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Which are π-bonded organometallic compounds?a)[Cr(η6 — (C6H6)]b)[Fe(CO)5]c)K[PtCI3η2 - C2H4]d)[Fe(η5 - C5H5)2]Correct answer is option 'A,C,D'. Can you explain this answer?
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