JEE Advanced (One or More Correct Option): Alcohols, Phenols & Ethers | Chapter-wise Tests for JEE Main & Advanced PDF Download

Q.1.
Product mixture would be
(a)
(b)
(c)
(d) none of these

Correct Answer is option (a, b, c)

The intermediate formed give the alkene in option (B) or (C) after rearrangement.

Q.2. Which among the following statement(s) about ethers is/are correct?
(a) Peroxide is obtained in presence of air
(b) Ethers are weakly acidic
(c) Ethers form oxonium salt
(d) Ethers form stable complexes with Lewis acids

Correct Answer is option (a, c, d)
(a) Fact
(c)
(d)

Q.3. Select wrong statements.
(a) Phenol react with Na₂CO₃ and liberates CO₂ gas
(b) Phenol turns blue litmus to red
(c) Reactivity of methanol with Na metal is more than that of isopropyl alcohol
(d) Methanol gives iodoform test

Correct Answer is option (a, d)

Q.4. 

Which of the following reagent can be used to differentiate between A and B?
(a) FeCl₃
(b) Active metal Na
(c) Lucas reagent
(d) K₂Cr₂O₇

Correct Answer is option (c, d)

2^o and 3^o Alcohol can be distinghished by Lucas reagent and K₂Cr₂O₇.

Q.5. Which of the following may undergo Reimer – Tiemann reaction?
(a)
(b)

(c)
(d)

Correct Answer is option (a, b)
Reimer – Tiemann reaction can be shown by and its derivative.

Q.6. In which of the reaction ring expansion take place when piratic acid is added in it?
(a)
(b)
(c)
(d)

Correct Answer is option (a, b)
5 membered ring is more stable than 4 membered ring because of less angle strain.

Q.7. Which of the following ethers will get hydrolysed by HI?
(a)
(b)
(c)
(d)

Correct Answer is option (c, d)
Aryl group can't participate in nucleophilic substitution reaction. Also, bridgehead carbon doesn't participate in nucleophilic substitution reaction.

Q.8. Which of the following alcohols will same alkene on reaction with conc. H₂SO₄ ?
(a)
(b)
(c)
(d)

Correct Answer is option (a, b, c)

Q.9. Which of the following compounds are oxidized by HIO₄ ?
(a)
(b)
(c)
(d)

Correct Answer is option (b, c, d)
α- Hydroxy ketone, α- Hydroxy aldehyde and α- Amino alcohol and vicinal – diol reacts with HIO_4.

Q.10. The correct combination of names for isomeric alcohols with molecular formula C₄H₁₀O is/are.
(a) tert-butanol and 2-methylpropan-2-ol
(b) tert-butanol and 1,1-dimethylethan-1-ol
(c) n-butanol and butan-1-ol
(d) Isobutyl alcohol and 2-methylpropan-1-ol

Correct Answer is option (a, c, d)
Isomeric alcohols of C₄H₁₀O are:

or