PHYSICAL PROPERTIES OF BASES
(i) Taste They are sharp bitter in taste.
(ii) Effect on skin They give a feeling of soapy touch and all alkali have a mild corrosive action on skin.
(iii) Effect on Indicator They affect the indicators as given below
Fig: Bases show various physical properties
Indicator | Change in acidic medium |
Red Litmus | Red to Blue |
Methyl orange | Orange to yellow |
Phenolphthalein | Colourless to pink |
Turmeric paper | Yellow to red brown |
Chemical Properties of Bases
2. Reaction with Metals
(i)
(ii)
2. Reaction of Bases with Non-metallic oxide
Base react with non-metallic oxide to form their respective carbonates and water.
(i)
(ii)
Some of the alkalis like sodium hydroxide (NaOH) are called deliquescent because they absorb carbon dioxide from the air and its strength decreases with time.
3. Reaction of Bases with Acids
They neutralise the acids to form salt and water.
Acid + Base → Salt + Water
4. Reaction of Bases with ammonium salt
Bases react with ammonium salt to evolve ammonia gas.
(i)
(ii)
5. Reaction of Bases with Salt
Bases react with salt solution to form another base and another salt.
(i)
(ii)
USES OF BASES
S.No. | Base | Use |
1 | Sodium hydroxide (NaOH ) | It is used in the manufacture of washing soap, paper, petrol refining and as a reagent in the laboratory. |
2 | Potassium hydroxide (KOH) | It is used in the manufacture of soap paper (bathing soap) and alkaline batteries. |
3 | Calcium hydroxide (Slaked lime) [Ca(OH)2] | It is used in the manufacture of bleaching powder and softening of hard water. |
4 | Magnesium hydroxide [Mg(OH)2] | It is used as an antacid. |
5 | Aluminum hydroxide [Al(OH)3] | It is used as a foaming agent in fire extinguishers. |
6 | Ammonium hydroxide (NH4OH) | It is used in removing grease stains from clothes |
7 | Sodium carbonate (Na2CO3) | It is used as a cleaning agent for domestic |
COMPARISON BETWEEN PROPERTIES OF ACIDS & BASES
S.no. | Acids | Bases |
(i) | Sour in taste | Bitter in taste |
(ii) | The properties are due to the presence of hydrogen ion (H+) in water solution of an acid | The properties are due to the presence of hydroxide ion (OH-) in water solution of a base. |
(iii) | Turns blue litmus to red | Turns red litmus to blue |
(iv) | Aqueous solution conducts electricity | Aqueous solution conducts electricity |
(v) | Reacts with active metals like Na, K, Ca and Zn to give hydrogen gas. | Does not react with metals except with Zn, Al and Sn. |
(vi) | Acidic properties disappear when react with bases (Neutralization) | Basic properties disappear when reacting with acids (Neutralization) |
(vii) | Reacts with carbonates to give carbon dioxide | Absorbs carbon dioxide to form carbonate. |
(viii) | Frequently corrosive to skin | Frequently corrosive to skin and slippery in nature. |
(ix) | The pH value is less than 7 at 25°C | The pH value is greater than 7 at 25°C |
Q.1. What do All Acids and Bases have in Common?
Ans. A common thing for all the acids is that they produce hydrogen ions [H+ (aq.)] when dissolved in water. For Ex, Acids like HCl, H2SO4, HNO3, CH3COOH etc. show acidic character because they dissociate in aqueous solution to produce hydrogen ions. But all the compounds containing hydrogen are not acids such as glucose (C6H12O6) and alcohol (C2H5OH) also contain hydrogen but they do not show acidic character.
Activity: To find the characteristics common between acids and bases.
Materials required: Dilute hydrochloric acid, Dilute sulphuric acid, Dilute solution of sodium hydroxide, Ethanol, Glucose solution & Beaker, Carbon electrodes, Dry cells, bulb 1.5 V, Key.
Procedure: Take a beaker and place two carbon electrodes into it.
Connect the electrodes to a battery bulb through a key and a dry cell. Pour dilute hydrochloric acid into the beaker and press the key. Did the bulb glow? Perform similar experiment with all the given solutions, and record your observations.
Observation
Solution | Bulb glows | Bulb does not glow | Nature of solution |
Dil. Hydrochloric acid | × | Conducting | |
Dil Sulphuric acid | × | Conducting | |
Dil. Sodium hydroxide | × | Conducting | |
Ethanol | × | Non- Conducting | |
Glucose solution | × | Non- Conducting |
Conclusion: The solutions of acids and bases are good conductors of electricity. The solution of glucose and ethanol are a nonconductor of electricity.
Bases: A common thing for all the bases (or ) is that they all produce hydroxide ions (OH-) when dissolved in water. For Example - NaOH, Mg(OH)2, Ca(OH)2 and NH4OH are all bases because they dissolve in water to produce hydroxide ion (OH-)
Acids or Bases (Alkali) in Water Solution-
The acidic behavior of acids due to the presence of hydrogen ions. H+ (aq) ions, in them. The acids produce hydrogen ions only in the presence of water. So, in the absence of water, a substance will not form hydrogen ions and hence will not show its acidic behavior.
Activity: To show that acids furnish H+ (aq) ions only in the presence of water.
Materials required: Common salt, Conc. sulphuric acid, anhydrous calcium chloride, blue litmus paper, boiling tube, delivery tube packed with anhydrous calcium chloride.
Procedure: Take 0.5g of dry common salt in a dry boiling tube. Add a few drops of concentrated sulphuric acid over common salt in the boiling tube. What do you see? A colourless, irritating gas is evolved. Fit a cork carrying a calcium chloride packed delivery tube into the mouth of the boiling tube.
Bring a dry blue litmus paper near the opening of the calcium
chloride tube. Observe, if there is any change in colour. Colour of the litmus paper remains unchanged. Now, bring a moistened blue litmus paper near the mouth of the calcium chloride tube. Do you observe any change in the color of litmus paper? Yes, blue litmus has changed to red.
From the above activity, following conclusion can be drawn :-
Conclusion: Dry HCl gas on coming in contact with dry blue litmus paper does not produce H+ ions, and hence the color of litmus paper does not change. so, we can say that separation of H+ ions form acid takes place only in the presence of water.
Q.2. Why should water be never added to dilution of an Acid?
Ans. Mixing of water in acid is an exothermic process and more heat has produced that splashing of water. In order to avoid this. We must add acid into water and not water into acid.
Moreover, acid must also be added to water in small lots and not in one installment.
Q.3. How Strong are Acid or Base Solution?
Ans. Acids and bases on dilution with water, decreases the concentration of H+(aq) or OH-(aq) ions in the acidic and basic solutions respectively.
If we find quantitatively, the amount of H+(aq) / OH-(aq) ions present in a solution, we can judge how strong an acid or a base is?
We can do this by the help of a universal indicator, which is a mixture of several indicators. The universal indicator shows different colors at different concentration of hydrogen ions or pH values in solution.
5 videos|292 docs|59 tests
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1. What are the physical properties of bases? |
2. What are the chemical properties of bases? |
3. What are some common examples of bases? |
4. How do bases differ from acids? |
5. What are the uses of bases? |
5 videos|292 docs|59 tests
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