Table of contents | |
Non-Newtonian Fluids | |
Compressibility | |
Surface Tension of Liquids | |
Capillarity | |
Vapour Pressure |
Consider a hypothetical fluid having a zero viscosity ( μ = 0). Such a fluid is called an ideal fluid and the resulting motion is called as ideal or inviscid flow. In an ideal flow, there is no existence of shear force because of vanishing viscosity.
Due to the deviation from Newton's law of viscosity they are commonly termed as non-Newtonian fluids. Figure 2.1 shows the class of fluid for which this relationship is nonlinear.
The phenomenon of surface tension arises due to the two kinds of intermolecular forces
(i) Cohesion : The force of attraction between the molecules of a liquid by virtue of which they are bound to each other to remain as one assemblage of particles is known as the force of cohesion. This property enables the liquid to resist tensile stress.
(ii) Adhesion : The force of attraction between unlike molecules, i.e. between the molecules of different liquids or between the molecules of a liquid and those of a solid body when they are in contact with each other, is known as the force of adhesion. This force enables two different liquids to adhere to each other or a liquid to adhere to a solid body or surface.
Figure 2.3 The intermolecular cohesive force field in a bulk of liquid with a free surface
A and B experience equal force of cohesion in all directions, C experiences a net force interior of the liquid The net force is maximum for D since it is at surface
Work is done on each molecule arriving at surface against the action of an inward force. Thus mechanical work is performed in creating a free surface or in increasing the area of the surface. Therefore, a surface requires mechanical energy for its formation and the existence of a free surface implies the presence of stored mechanical energy known as free surface energy. Any system tries to attain the condition of stable equilibrium with its potential energy as minimum. Thus a quantity of liquid will adjust its shape until its surface area and consequently its free surface energy is a minimum.
The magnitude of surface tension is defined as the tensile force acting across imaginary short and straight elemental line divided by the length of the line.
The dimensional formula is F/L or MT-2 . It is usually expressed in N/m in SI units.
Surface tension is a binary property of the liquid and gas or two liquids which are in contact with each other and defines the interface. It decreases slightly with increasing temperature. The surface tension of water in contact with air at 20°C is about 0.073 N/m.
The interplay of the forces of cohesion and adhesion explains the phenomenon of capillarity. When a liquid is in contact with a solid, if the forces of adhesion between the molecules of the liquid and the solid are greater than the forces of cohesion among the liquid molecules themselves, the liquid molecules crowd towards the solid surface. The area of contact between the liquid and solid increases and the liquid thus wets the solid surface.
The reverse phenomenon takes place when the force of cohesion is greater than the force of adhesion. These adhesion and cohesion properties result in the phenomenon of capillarity by which a liquid either rises or falls in a tube dipped into the liquid depending upon whether the force of adhesion is more than that of cohesion or not (Fig.2.4).
56 videos|104 docs|75 tests
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1. What are non-Newtonian fluids? |
2. How does compressibility affect fluids? |
3. What is surface tension of liquids? |
4. How does capillarity work in liquids? |
5. What is the significance of vapor pressure in liquids? |
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